Novel C-3 Epimerization of Digitoxosides to Olivosides under Hydrogenolysis Conditions

Kazunobu Toshima, Kyoko Inagaki, Masaya Nakata, Shuichi Matsumura

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

The treatment of several β-digitoxosides with hydrogen in the presence of a catalytic amount of Raney-Ni (W4) in MeOH at 50°C under neutral conditions afforded the C-3 epimers, β-olivosides, in good yields.

Original languageEnglish
Pages (from-to)695-696
Number of pages2
JournalSynlett
Volume1997
Issue number6
DOIs
Publication statusPublished - 1997 Jan 1

ASJC Scopus subject areas

  • Organic Chemistry

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