Abstract
Redox flow batteries (RFBs) have emerged as a promising candidate for large-scale energy storage because of the flexible design for high energy, power, and safety. In this study, FeCl3·6H2O/urea composite deep eutectic catholyte (FeU-DEC)-infused self-standing carbon nanofiber (CNF) was synthesized for green and high power density RFB through industrially available processes. FeU-DEC-infused CNF displayed an extremely high power density (874 mW/g) as well as high capacity (27.28 mAh/g) derived from high theoretical capacity of FeU-DEC (89.24 mAh/g) in addition to the advantages of the FeU-DEC characteristics (e.g., nonflammable, biodegradable, facile preparation). This is because of the large electroactive area derived from the high surface area of CNF and superlyophilicity of FeU-DEC on CNFs. Furthermore, we compared the wettability of CNF with other electrodes, as well as the chemical stability and electrode performance, based on topological wetting analysis using parameters of fiber radius, fiber interval, the equilibrium contact angle of FeU-DEC on electrodes, and surface tension of FeU-DEC, giving wetting threshold for FeU-DEC on fibrous electrodes. The wetting analysis are applied not only for FeU-DEC, but also for a wide range of other DECs and deep eutectic anolyte. This work contributes to the further development of green and high-performance RFBs.
| Original language | English |
|---|---|
| Pages (from-to) | 15742-15750 |
| Number of pages | 9 |
| Journal | Unknown Journal |
| Volume | 10 |
| Issue number | 18 |
| DOIs | |
| Publication status | Published - 2018 May 9 |
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Keywords
- carbon nanofiber
- deep eutectic solvent
- electrospinning
- redox flow battery
- wettability
ASJC Scopus subject areas
- Materials Science(all)
Cite this
Novel Deep-Eutectic-Solvent-Infused Carbon Nanofiber Networks as High Power Density Green Battery Cathodes. / Kawase, Koki; Abe, Jyunichiro; Tenjimbayashi, Mizuki; Kobayashi, Yuta; Takahashi, Keisuke; Shiratori, Seimei.
In: Unknown Journal, Vol. 10, No. 18, 09.05.2018, p. 15742-15750.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Novel Deep-Eutectic-Solvent-Infused Carbon Nanofiber Networks as High Power Density Green Battery Cathodes
AU - Kawase, Koki
AU - Abe, Jyunichiro
AU - Tenjimbayashi, Mizuki
AU - Kobayashi, Yuta
AU - Takahashi, Keisuke
AU - Shiratori, Seimei
PY - 2018/5/9
Y1 - 2018/5/9
N2 - Redox flow batteries (RFBs) have emerged as a promising candidate for large-scale energy storage because of the flexible design for high energy, power, and safety. In this study, FeCl3·6H2O/urea composite deep eutectic catholyte (FeU-DEC)-infused self-standing carbon nanofiber (CNF) was synthesized for green and high power density RFB through industrially available processes. FeU-DEC-infused CNF displayed an extremely high power density (874 mW/g) as well as high capacity (27.28 mAh/g) derived from high theoretical capacity of FeU-DEC (89.24 mAh/g) in addition to the advantages of the FeU-DEC characteristics (e.g., nonflammable, biodegradable, facile preparation). This is because of the large electroactive area derived from the high surface area of CNF and superlyophilicity of FeU-DEC on CNFs. Furthermore, we compared the wettability of CNF with other electrodes, as well as the chemical stability and electrode performance, based on topological wetting analysis using parameters of fiber radius, fiber interval, the equilibrium contact angle of FeU-DEC on electrodes, and surface tension of FeU-DEC, giving wetting threshold for FeU-DEC on fibrous electrodes. The wetting analysis are applied not only for FeU-DEC, but also for a wide range of other DECs and deep eutectic anolyte. This work contributes to the further development of green and high-performance RFBs.
AB - Redox flow batteries (RFBs) have emerged as a promising candidate for large-scale energy storage because of the flexible design for high energy, power, and safety. In this study, FeCl3·6H2O/urea composite deep eutectic catholyte (FeU-DEC)-infused self-standing carbon nanofiber (CNF) was synthesized for green and high power density RFB through industrially available processes. FeU-DEC-infused CNF displayed an extremely high power density (874 mW/g) as well as high capacity (27.28 mAh/g) derived from high theoretical capacity of FeU-DEC (89.24 mAh/g) in addition to the advantages of the FeU-DEC characteristics (e.g., nonflammable, biodegradable, facile preparation). This is because of the large electroactive area derived from the high surface area of CNF and superlyophilicity of FeU-DEC on CNFs. Furthermore, we compared the wettability of CNF with other electrodes, as well as the chemical stability and electrode performance, based on topological wetting analysis using parameters of fiber radius, fiber interval, the equilibrium contact angle of FeU-DEC on electrodes, and surface tension of FeU-DEC, giving wetting threshold for FeU-DEC on fibrous electrodes. The wetting analysis are applied not only for FeU-DEC, but also for a wide range of other DECs and deep eutectic anolyte. This work contributes to the further development of green and high-performance RFBs.
KW - carbon nanofiber
KW - deep eutectic solvent
KW - electrospinning
KW - redox flow battery
KW - wettability
UR - http://www.scopus.com/inward/record.url?scp=85046408285&partnerID=8YFLogxK
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U2 - 10.1021/acsami.8b03099
DO - 10.1021/acsami.8b03099
M3 - Article
AN - SCOPUS:85046408285
VL - 10
SP - 15742
EP - 15750
JO - Mathematical Social Sciences
JF - Mathematical Social Sciences
SN - 0165-4896
IS - 18
ER -