Abstract
n-Butyl 2-amino-2-deoxy-β-D-glucopyranoside (C4GlcN) was prepared by the novel direct transglycosylation reaction of chitosan and n-butanol using the resting cells of Penicillium funiculosum KY616 as the enzyme source of exo-β-D-glucosaminidase. Using this strain, a versatile synthetic intermediate, C4GlcN, was prepared in a yield of 210 mg/g chitosan when chitosan and n-butanol were incubated at a temperature of 30 °C and pH 4 for 2 d.
| Original language | English |
|---|---|
| Pages (from-to) | 373-374 |
| Number of pages | 2 |
| Journal | Chemistry Letters |
| Issue number | 5 |
| Publication status | Published - 1999 |
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ASJC Scopus subject areas
- Chemistry(all)
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Novel direct preparation of n-butyl 2-amino-2-deoxy-β-D-glucopyranoside from chitosan and n-butanol using biocatalyst. / Matsumura, Shuichi; Yao, Eiya; Sakiyama, Kazuya; Toshima, Kazunobu.
In: Chemistry Letters, No. 5, 1999, p. 373-374.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Novel direct preparation of n-butyl 2-amino-2-deoxy-β-D-glucopyranoside from chitosan and n-butanol using biocatalyst
AU - Matsumura, Shuichi
AU - Yao, Eiya
AU - Sakiyama, Kazuya
AU - Toshima, Kazunobu
PY - 1999
Y1 - 1999
N2 - n-Butyl 2-amino-2-deoxy-β-D-glucopyranoside (C4GlcN) was prepared by the novel direct transglycosylation reaction of chitosan and n-butanol using the resting cells of Penicillium funiculosum KY616 as the enzyme source of exo-β-D-glucosaminidase. Using this strain, a versatile synthetic intermediate, C4GlcN, was prepared in a yield of 210 mg/g chitosan when chitosan and n-butanol were incubated at a temperature of 30 °C and pH 4 for 2 d.
AB - n-Butyl 2-amino-2-deoxy-β-D-glucopyranoside (C4GlcN) was prepared by the novel direct transglycosylation reaction of chitosan and n-butanol using the resting cells of Penicillium funiculosum KY616 as the enzyme source of exo-β-D-glucosaminidase. Using this strain, a versatile synthetic intermediate, C4GlcN, was prepared in a yield of 210 mg/g chitosan when chitosan and n-butanol were incubated at a temperature of 30 °C and pH 4 for 2 d.
UR - http://www.scopus.com/inward/record.url?scp=0033451108&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0033451108&partnerID=8YFLogxK
M3 - Article
AN - SCOPUS:0033451108
SP - 373
EP - 374
JO - Chemistry Letters
JF - Chemistry Letters
SN - 0366-7022
IS - 5
ER -