Novel direct preparation of n-butyl 2-amino-2-deoxy-β-D-glucopyranoside from chitosan and n-butanol using biocatalyst

Shuichi Matsumura, Eiya Yao, Kazuya Sakiyama, Kazunobu Toshima

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4 Citations (Scopus)

Abstract

n-Butyl 2-amino-2-deoxy-β-D-glucopyranoside (C4GlcN) was prepared by the novel direct transglycosylation reaction of chitosan and n-butanol using the resting cells of Penicillium funiculosum KY616 as the enzyme source of exo-β-D-glucosaminidase. Using this strain, a versatile synthetic intermediate, C4GlcN, was prepared in a yield of 210 mg/g chitosan when chitosan and n-butanol were incubated at a temperature of 30 °C and pH 4 for 2 d.

Original languageEnglish
Pages (from-to)373-374
Number of pages2
JournalChemistry Letters
Issue number5
DOIs
Publication statusPublished - 1999 Jan 1

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ASJC Scopus subject areas

  • Chemistry(all)

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