Novel glycosidations of glycals using BCl3 or BBr3 as a promoter for catalytic and stereoselective syntheses of 2-deoxy-α-glycosides

Kazunobu Toshima, Hideyuki Nagai, Yasunobu Ushiki, Shuichi Matsumura

Research output: Contribution to journalArticle

43 Citations (Scopus)

Abstract

The glycosidations of silylated glycals and alcohols using a catalytic amount of BCl3 or BBr3 proceeded under mild conditions in a highly stereoselective fashion to afford the corresponding 2-deoxy-α-glycosides in high yields which were often found as the glycosidic components of several bioactive natural products.

Original languageEnglish
Pages (from-to)1007-1009
Number of pages3
JournalSynlett
Issue number9
DOIs
Publication statusPublished - 1998 Sep

ASJC Scopus subject areas

  • Organic Chemistry

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