Abstract
In this short review article, several glycosylation methods that were developed in our laboratories, including stereocontrolled glycosylation using 2,6-anhydro-2,6-dideoxy-2,6-dithio sugars for obtaining 2,6-dideoxy glycosides, C-glycosylation employing unprotected sugars, environmentally benign glycosylation utilizing heterogeneous solid acids and ionic liquids, are recounted. In addition, representative and significant applications of these methods to the synthesis of complex natural products are described.
| Original language | English |
|---|---|
| Pages (from-to) | 1282-1297 |
| Number of pages | 16 |
| Journal | Carbohydrate Research |
| Volume | 341 |
| Issue number | 10 |
| DOIs | |
| Publication status | Published - 2006 Jul 24 |
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Keywords
- Carbohydrate
- Glycomolecule
- Glycoside
- Glycosylation
- Natural product
ASJC Scopus subject areas
- Biochemistry
- Molecular Biology
- Organic Chemistry
Cite this
Novel glycosylation methods and their application to natural products synthesis. / Toshima, Kazunobu.
In: Carbohydrate Research, Vol. 341, No. 10, 24.07.2006, p. 1282-1297.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Novel glycosylation methods and their application to natural products synthesis
AU - Toshima, Kazunobu
PY - 2006/7/24
Y1 - 2006/7/24
N2 - In this short review article, several glycosylation methods that were developed in our laboratories, including stereocontrolled glycosylation using 2,6-anhydro-2,6-dideoxy-2,6-dithio sugars for obtaining 2,6-dideoxy glycosides, C-glycosylation employing unprotected sugars, environmentally benign glycosylation utilizing heterogeneous solid acids and ionic liquids, are recounted. In addition, representative and significant applications of these methods to the synthesis of complex natural products are described.
AB - In this short review article, several glycosylation methods that were developed in our laboratories, including stereocontrolled glycosylation using 2,6-anhydro-2,6-dideoxy-2,6-dithio sugars for obtaining 2,6-dideoxy glycosides, C-glycosylation employing unprotected sugars, environmentally benign glycosylation utilizing heterogeneous solid acids and ionic liquids, are recounted. In addition, representative and significant applications of these methods to the synthesis of complex natural products are described.
KW - Carbohydrate
KW - Glycomolecule
KW - Glycoside
KW - Glycosylation
KW - Natural product
UR - http://www.scopus.com/inward/record.url?scp=33747036462&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=33747036462&partnerID=8YFLogxK
U2 - 10.1016/j.carres.2006.03.012
DO - 10.1016/j.carres.2006.03.012
M3 - Article
C2 - 16630601
AN - SCOPUS:33747036462
VL - 341
SP - 1282
EP - 1297
JO - Carbohydrate Research
JF - Carbohydrate Research
SN - 0008-6215
IS - 10
ER -