Novel lipase-catalyzed ring-opening copolymerization of oxiranes and dicarboxylic anhydride forming polyesters bearing carboxyl groups and their physicochemical properties and biodegradability

Shuichi Matsumura, Takeshi Okamoto, Keisuke Tsukada, Noriyuki Mizutani, Kazunobu Toshima

Research output: Chapter in Book/Report/Conference proceedingChapter

13 Citations (Scopus)

Abstract

Oxiranes, such as benzyl glycidate and glycidyl phenyl ether, were copolymerized with dicarboxylic anhydride by lipase at a temperature between 60 and 80°C to yield the corresponding polyesters bearing carboxyl or phenyl groups. Bulk polymerization, especially at 80°C, and preferably using porcine pancreatic lipase, gave biodegradable polyesters with a molecular weight of greater than 10000. Poly(sodium carboxylate)s containing ester linkages in the backbone prepared in this study were readily biodegradable by the activated sludge and exhibited a calcium ion sequestration capacity.

Original languageEnglish
Title of host publicationMacromolecular Symposia
Pages219-235
Number of pages17
Volume144
Publication statusPublished - 1999

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ASJC Scopus subject areas

  • Materials Chemistry
  • Polymers and Plastics

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