Novel spin transition between S = 5/2 and S = 3/2 in highly saddled iron(III) porphyrin complexes at extremely low temperatures

Yoshiki Ohgo, Yuya Chiba, Daisuke Hashizume, Hidehiro Uekusa, Tomoji Ozeki, Mikio Nakamura

Research output: Contribution to journalArticle

25 Citations (Scopus)

Abstract

A novel spin transition between S = 5/2 and S = 3/2 has been observed for the first time in five-coordinate, highly saddled iron(iii) porphyrinates by EPR and SQUID measurements at extremely low temperatures.

Original languageEnglish
Pages (from-to)1935-1937
Number of pages3
JournalChemical Communications
Issue number18
DOIs
Publication statusPublished - 2006

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SQUIDs
Porphyrins
Paramagnetic resonance
Iron
Temperature

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Novel spin transition between S = 5/2 and S = 3/2 in highly saddled iron(III) porphyrin complexes at extremely low temperatures. / Ohgo, Yoshiki; Chiba, Yuya; Hashizume, Daisuke; Uekusa, Hidehiro; Ozeki, Tomoji; Nakamura, Mikio.

In: Chemical Communications, No. 18, 2006, p. 1935-1937.

Research output: Contribution to journalArticle

Ohgo, Yoshiki ; Chiba, Yuya ; Hashizume, Daisuke ; Uekusa, Hidehiro ; Ozeki, Tomoji ; Nakamura, Mikio. / Novel spin transition between S = 5/2 and S = 3/2 in highly saddled iron(III) porphyrin complexes at extremely low temperatures. In: Chemical Communications. 2006 ; No. 18. pp. 1935-1937.
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