Novel spin transition between S = 5/2 and S = 3/2 in highly saddled iron(III) porphyrin complexes at extremely low temperatures

Yoshiki Ohgo, Yuya Chiba, Daisuke Hashizume, Hidehiro Uekusa, Tomoji Ozeki, Mikio Nakamura

Research output: Contribution to journalArticle

25 Citations (Scopus)

Abstract

A novel spin transition between S = 5/2 and S = 3/2 has been observed for the first time in five-coordinate, highly saddled iron(iii) porphyrinates by EPR and SQUID measurements at extremely low temperatures.

Original languageEnglish
Pages (from-to)1935-1937
Number of pages3
JournalChemical Communications
Issue number18
DOIs
Publication statusPublished - 2006

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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