N2O oxidation of phosphines catalyzed by low-valent nickel complexes

Tohru Yamada; Kyosuke Suzuki; Kentaro Hashimoto; Taketo Ikeno

doi:10.1246/cl.1999.1043

N₂O oxidation of phosphines catalyzed by low-valent nickel complexes

Tohru Yamada, Kyosuke Suzuki, Kentaro Hashimoto, Taketo Ikeno

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

19 Citations (Scopus)

Abstract

In the presence of a catalytic amount of the nickel(0) complex derived from Ni(acac)₂ or NiCl₂ with DIBAL or BuLi, nitrous oxide (N₂O) was captured and activated to oxidize phosphine(III) into the corresponding phosphine oxide. Bidentate phosphines, for example, 1,3-bis(diphenyl-phosphino)propane (dppp), were employed as effective ligands for N₂O; oxidation and were recovered after the reaction.

Original language	English
Pages (from-to)	1043-1044
Number of pages	2
Journal	Chemistry Letters
Issue number	10
DOIs	https://doi.org/10.1246/cl.1999.1043
Publication status	Published - 1999

ASJC Scopus subject areas

Chemistry(all)

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10.1246/cl.1999.1043

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abstract = "In the presence of a catalytic amount of the nickel(0) complex derived from Ni(acac)2 or NiCl2 with DIBAL or BuLi, nitrous oxide (N2O) was captured and activated to oxidize phosphine(III) into the corresponding phosphine oxide. Bidentate phosphines, for example, 1,3-bis(diphenyl-phosphino)propane (dppp), were employed as effective ligands for N2O; oxidation and were recovered after the reaction.",

author = "Tohru Yamada and Kyosuke Suzuki and Kentaro Hashimoto and Taketo Ikeno",

year = "1999",

doi = "10.1246/cl.1999.1043",

language = "English",

pages = "1043--1044",

journal = "Chemistry Letters",

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publisher = "Chemical Society of Japan",

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T1 - N2O oxidation of phosphines catalyzed by low-valent nickel complexes

AU - Yamada, Tohru

AU - Suzuki, Kyosuke

AU - Hashimoto, Kentaro

AU - Ikeno, Taketo

PY - 1999

Y1 - 1999

N2 - In the presence of a catalytic amount of the nickel(0) complex derived from Ni(acac)2 or NiCl2 with DIBAL or BuLi, nitrous oxide (N2O) was captured and activated to oxidize phosphine(III) into the corresponding phosphine oxide. Bidentate phosphines, for example, 1,3-bis(diphenyl-phosphino)propane (dppp), were employed as effective ligands for N2O; oxidation and were recovered after the reaction.

AB - In the presence of a catalytic amount of the nickel(0) complex derived from Ni(acac)2 or NiCl2 with DIBAL or BuLi, nitrous oxide (N2O) was captured and activated to oxidize phosphine(III) into the corresponding phosphine oxide. Bidentate phosphines, for example, 1,3-bis(diphenyl-phosphino)propane (dppp), were employed as effective ligands for N2O; oxidation and were recovered after the reaction.

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U2 - 10.1246/cl.1999.1043

DO - 10.1246/cl.1999.1043

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JO - Chemistry Letters

JF - Chemistry Letters

IS - 10

ER -

N₂O oxidation of phosphines catalyzed by low-valent nickel complexes

Abstract

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