Olefin polymerization catalyzed by homoor heterobimetallic zirconocene complex/methylaluminoxane system

Makoto Mitani, Kunihiro Oouchi, Michiya Hayakawa, Tohru Yamada, Teruaki Mukaiyama

Research output: Contribution to journalArticle

17 Citations (Scopus)

Abstract

Polymerization of ethylene and copolymerization of ethylene-propylene proceeded smoothly by using homometallic binuclear zirconium complex 1 or heterometallic binuclear zirconium-titanium complex 2/methylaluminoxane catalyst system. The molecular weight distributions of polymers obtained by the binuclear zirconium complexes were broader than that produced by mononuclear zirconium complex.

Original languageEnglish
Pages (from-to)677-682
Number of pages6
JournalPolymer Bulletin
Volume35
Issue number6
DOIs
Publication statusPublished - 1995 Dec
Externally publishedYes

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Alkenes
complex systems
Zirconium
alkenes
Olefins
Large scale systems
polymerization
Polymerization
Ethylene
ethylene
copolymerization
Molecular weight distribution
Titanium
propylene
Copolymerization
Propylene
molecular weight
Polymers
titanium
catalysts

ASJC Scopus subject areas

  • Polymers and Plastics
  • Materials Chemistry

Cite this

Olefin polymerization catalyzed by homoor heterobimetallic zirconocene complex/methylaluminoxane system. / Mitani, Makoto; Oouchi, Kunihiro; Hayakawa, Michiya; Yamada, Tohru; Mukaiyama, Teruaki.

In: Polymer Bulletin, Vol. 35, No. 6, 12.1995, p. 677-682.

Research output: Contribution to journalArticle

Mitani, Makoto ; Oouchi, Kunihiro ; Hayakawa, Michiya ; Yamada, Tohru ; Mukaiyama, Teruaki. / Olefin polymerization catalyzed by homoor heterobimetallic zirconocene complex/methylaluminoxane system. In: Polymer Bulletin. 1995 ; Vol. 35, No. 6. pp. 677-682.
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