Olefin polymerization catalyzed by homoor heterobimetallic zirconocene complex/methylaluminoxane system

Makoto Mitani, Kunihiro Oouchi, Michiya Hayakawa, Tohru Yamada, Teruaki Mukaiyama

Research output: Contribution to journalArticle

18 Citations (Scopus)

Abstract

Polymerization of ethylene and copolymerization of ethylene-propylene proceeded smoothly by using homometallic binuclear zirconium complex 1 or heterometallic binuclear zirconium-titanium complex 2/methylaluminoxane catalyst system. The molecular weight distributions of polymers obtained by the binuclear zirconium complexes were broader than that produced by mononuclear zirconium complex.

Original languageEnglish
Pages (from-to)677-682
Number of pages6
JournalPolymer Bulletin
Volume35
Issue number6
DOIs
Publication statusPublished - 1995 Dec 1
Externally publishedYes

ASJC Scopus subject areas

  • Chemistry(all)
  • Condensed Matter Physics
  • Polymers and Plastics
  • Materials Chemistry

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