Abstract
Three one-dimensional (1D) heterospin trimetallic chain-like polymers [{LCu(H2O)}Ln(MeOH)(H2O)2{(μ-CN)2Fe(CN)4}]·2H2O (1, Ln = La; 2, Ln = Nd; 3, Ln = Gd) were prepared by substitution of the nitrato ligands in [LCuLn] complexes with [Fe(CN)6]3- ions (H2L = N,N′-bis(3-methoxysalicylidene)propane-1,2-diamine). Single-crystal X-ray diffraction analysis revealed that the methyl on the salen-type ligand impeded the connection between cyanide groups and Cu(II) ions efficiently. Consequently, three novel one-dimensional (1D) trimetallic chain-like polymers were obtained with the linker [Fe(CN)6]3- ions interacting only with the lanthanide ions. The magnetic investigation for 3 indicated a ferrimagnetic chain may form.
| Original language | English |
|---|---|
| Pages (from-to) | 171-174 |
| Number of pages | 4 |
| Journal | Inorganic Chemistry Communications |
| Volume | 13 |
| Issue number | 1 |
| DOIs | |
| Publication status | Published - 2010 Jan |
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Keywords
- Heterospin
- Magnetic properties
- Salen-type ligand
- Structure
- Trimetallic polymer
ASJC Scopus subject areas
- Inorganic Chemistry
- Physical and Theoretical Chemistry
- Materials Chemistry
Cite this
One-dimensional salen-type heterospin trimetallic (3d-4f-3d′) chain-like coordination polymers : Syntheses, crystal structures and magnetic properties. / Sun, Wen Bin; Yan, Peng Fei; Li, Guang Ming; Zhang, Ju Wen; Gao, Ting; Suda, Masayuki; Einaga, Yasuaki.
In: Inorganic Chemistry Communications, Vol. 13, No. 1, 01.2010, p. 171-174.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - One-dimensional salen-type heterospin trimetallic (3d-4f-3d′) chain-like coordination polymers
T2 - Syntheses, crystal structures and magnetic properties
AU - Sun, Wen Bin
AU - Yan, Peng Fei
AU - Li, Guang Ming
AU - Zhang, Ju Wen
AU - Gao, Ting
AU - Suda, Masayuki
AU - Einaga, Yasuaki
PY - 2010/1
Y1 - 2010/1
N2 - Three one-dimensional (1D) heterospin trimetallic chain-like polymers [{LCu(H2O)}Ln(MeOH)(H2O)2{(μ-CN)2Fe(CN)4}]·2H2O (1, Ln = La; 2, Ln = Nd; 3, Ln = Gd) were prepared by substitution of the nitrato ligands in [LCuLn] complexes with [Fe(CN)6]3- ions (H2L = N,N′-bis(3-methoxysalicylidene)propane-1,2-diamine). Single-crystal X-ray diffraction analysis revealed that the methyl on the salen-type ligand impeded the connection between cyanide groups and Cu(II) ions efficiently. Consequently, three novel one-dimensional (1D) trimetallic chain-like polymers were obtained with the linker [Fe(CN)6]3- ions interacting only with the lanthanide ions. The magnetic investigation for 3 indicated a ferrimagnetic chain may form.
AB - Three one-dimensional (1D) heterospin trimetallic chain-like polymers [{LCu(H2O)}Ln(MeOH)(H2O)2{(μ-CN)2Fe(CN)4}]·2H2O (1, Ln = La; 2, Ln = Nd; 3, Ln = Gd) were prepared by substitution of the nitrato ligands in [LCuLn] complexes with [Fe(CN)6]3- ions (H2L = N,N′-bis(3-methoxysalicylidene)propane-1,2-diamine). Single-crystal X-ray diffraction analysis revealed that the methyl on the salen-type ligand impeded the connection between cyanide groups and Cu(II) ions efficiently. Consequently, three novel one-dimensional (1D) trimetallic chain-like polymers were obtained with the linker [Fe(CN)6]3- ions interacting only with the lanthanide ions. The magnetic investigation for 3 indicated a ferrimagnetic chain may form.
KW - Heterospin
KW - Magnetic properties
KW - Salen-type ligand
KW - Structure
KW - Trimetallic polymer
UR - http://www.scopus.com/inward/record.url?scp=72249102586&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=72249102586&partnerID=8YFLogxK
U2 - 10.1016/j.inoche.2009.11.006
DO - 10.1016/j.inoche.2009.11.006
M3 - Article
AN - SCOPUS:72249102586
VL - 13
SP - 171
EP - 174
JO - Inorganic Chemistry Communication
JF - Inorganic Chemistry Communication
SN - 1387-7003
IS - 1
ER -