One-dimensional salen-type heterospin trimetallic (3d-4f-3d′) chain-like coordination polymers: Syntheses, crystal structures and magnetic properties

Wen Bin Sun, Peng Fei Yan, Guang Ming Li, Ju Wen Zhang, Ting Gao, Masayuki Suda, Yasuaki Einaga

Research output: Contribution to journalArticle

27 Citations (Scopus)

Abstract

Three one-dimensional (1D) heterospin trimetallic chain-like polymers [{LCu(H2O)}Ln(MeOH)(H2O)2{(μ-CN)2Fe(CN)4}]·2H2O (1, Ln = La; 2, Ln = Nd; 3, Ln = Gd) were prepared by substitution of the nitrato ligands in [LCuLn] complexes with [Fe(CN)6]3- ions (H2L = N,N′-bis(3-methoxysalicylidene)propane-1,2-diamine). Single-crystal X-ray diffraction analysis revealed that the methyl on the salen-type ligand impeded the connection between cyanide groups and Cu(II) ions efficiently. Consequently, three novel one-dimensional (1D) trimetallic chain-like polymers were obtained with the linker [Fe(CN)6]3- ions interacting only with the lanthanide ions. The magnetic investigation for 3 indicated a ferrimagnetic chain may form.

Original languageEnglish
Pages (from-to)171-174
Number of pages4
JournalInorganic Chemistry Communications
Volume13
Issue number1
DOIs
Publication statusPublished - 2010 Jan

Fingerprint

coordination polymers
Magnetic properties
Polymers
Crystal structure
Ions
magnetic properties
crystal structure
synthesis
ions
Ligands
Lanthanoid Series Elements
Propane
ligands
Diamines
Cyanides
polymers
cyanides
diamines
Rare earth elements
propane

Keywords

  • Heterospin
  • Magnetic properties
  • Salen-type ligand
  • Structure
  • Trimetallic polymer

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Physical and Theoretical Chemistry
  • Materials Chemistry

Cite this

One-dimensional salen-type heterospin trimetallic (3d-4f-3d′) chain-like coordination polymers : Syntheses, crystal structures and magnetic properties. / Sun, Wen Bin; Yan, Peng Fei; Li, Guang Ming; Zhang, Ju Wen; Gao, Ting; Suda, Masayuki; Einaga, Yasuaki.

In: Inorganic Chemistry Communications, Vol. 13, No. 1, 01.2010, p. 171-174.

Research output: Contribution to journalArticle

Sun, Wen Bin ; Yan, Peng Fei ; Li, Guang Ming ; Zhang, Ju Wen ; Gao, Ting ; Suda, Masayuki ; Einaga, Yasuaki. / One-dimensional salen-type heterospin trimetallic (3d-4f-3d′) chain-like coordination polymers : Syntheses, crystal structures and magnetic properties. In: Inorganic Chemistry Communications. 2010 ; Vol. 13, No. 1. pp. 171-174.
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