Optically active aldiminato cobalt(II) complex catalyst for enantioselective hetero Diels-Alder reaction

Tohru Yamada, Satoko Kezuka, Tsuyoshi Mita, Taketo Ikeno

Research output: Contribution to journalArticle

18 Citations (Scopus)

Abstract

Among various aldiminato metal complexes, the optically active cobalt(II) complex efficiently catalyzed the enantioselective hetero Diels- Alder reaction of aromatic aldehydes with 1-methoxy-[3-(tert- butyldimethylsilyl)oxy]1,3-butadiene. In the presence of 0.5 mol% of the catalyst, the reaction smoothly proceeded and ortho substituents of the dienophiles that could chelate to the catalyst significantly accelerated the reaction to improve the chemical and optical yields.

Original languageEnglish
Pages (from-to)1041-1045
Number of pages5
JournalHeterocycles
Volume52
Issue number3
Publication statusPublished - 2000 Mar 1

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Coordination Complexes
Cycloaddition Reaction
Cobalt
Aldehydes
Catalysts
1,3-butadiene

ASJC Scopus subject areas

  • Organic Chemistry

Cite this

Optically active aldiminato cobalt(II) complex catalyst for enantioselective hetero Diels-Alder reaction. / Yamada, Tohru; Kezuka, Satoko; Mita, Tsuyoshi; Ikeno, Taketo.

In: Heterocycles, Vol. 52, No. 3, 01.03.2000, p. 1041-1045.

Research output: Contribution to journalArticle

Yamada, Tohru ; Kezuka, Satoko ; Mita, Tsuyoshi ; Ikeno, Taketo. / Optically active aldiminato cobalt(II) complex catalyst for enantioselective hetero Diels-Alder reaction. In: Heterocycles. 2000 ; Vol. 52, No. 3. pp. 1041-1045.
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