Oxo-Thiolation of Cationically Polymerizable Alkenes Using Flow Microreactors

Yosuke Ashikari, Kodai Saito, Toshiki Nokami, Jun ichi Yoshida, Aiichiro Nagaki

Research output: Contribution to journalArticlepeer-review

5 Citations (Scopus)

Abstract

The present study describes the cationic oxo-thiolation of polymerizable alkenes by using highly reactive cationic species generated by anodic oxidation. These highly reactive cations were able to activate alkenes before their polymerization. Fast mixing in flow microreactors effectively controlled chemoselectivity, enabling higher reaction temperatures.

Original languageEnglish
Pages (from-to)15239-15243
Number of pages5
JournalChemistry - A European Journal
Volume25
Issue number67
DOIs
Publication statusPublished - 2019 Dec 2

Keywords

  • alkenes
  • anodic oxidation
  • cationics
  • electrochemistry
  • flow microreactors
  • polymerization

ASJC Scopus subject areas

  • Catalysis
  • Organic Chemistry

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