Palladium-catalyzed Aromatic C−H Functionalizations Utilizing Electrochemical Oxidations

Research output: Contribution to journalReview articlepeer-review

Abstract

Transition-metal-catalyzed electrochemical C−H functionalizations have been extensively studied as atom- and step-economical clean methods in organic synthesis. In this account, we described our efforts on the palladium-catalyzed electrochemical C−H functionalizations, including C−H halogenations of arylpyridines and benzamide derivatives using HCl/HBr and I2 as a halogen source, a one-pot process giving teraryls via the palladium-catalyzed electrochemical C−H iodination and subsequent Suzuki-Miyaura coupling, and an iodine-mediated oxidative homo-coupling reaction of arylpyridines.

Original languageEnglish
JournalChemical Record
DOIs
Publication statusAccepted/In press - 2021

Keywords

  • C−H activation
  • C−H halogenation
  • electrochemical oxidation
  • oxidative homocoupling
  • palladium catalyst

ASJC Scopus subject areas

  • Chemistry(all)
  • Biochemistry
  • Chemical Engineering(all)
  • Materials Chemistry

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