Paramagnetic phase of a heavy-fermion compound, CeFePO, probed by< 57Fe mössbauer spectroscopy

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6 Citations (Scopus)


57Fe Mössbauer spectroscopy was applied to an iron-based layered compound CeFePO. At temperatures from 9.4 to 293 K, no magnetic splitting was observed in the Mössbauer spectra of CeFePO indicating a paramagnetic phase of the Fe magnetic sublattice. All the spectra were fitted with a small quadrupole splitting, and the Debye temperature of CeFePO was found to be ∼448 K. The isomer shift at room temperature, 0.32 mm/s, was almost equal to those of LnFeAsO (Ln = La, Ce, Sm). Comparing s-electron density using the isomer shifts and unit cell volumes, it was found that the Fe of CeFePO has a similar valence state to other layered iron-based quaternary oxypnictides except LaFePO.

Original languageEnglish
Article number064714
JournalJournal of the Physical Society of Japan
Issue number6
Publication statusPublished - 2012 Jun


  • CeFeAsO
  • CeFePO
  • Fe Mössbauer spectroscopy
  • Heavy fermion
  • Layered compounds

ASJC Scopus subject areas

  • Physics and Astronomy(all)


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