Peculiar atomic dynamics in liquid GeTe with asymmetrical bonding

Observation by inelastic x-ray scattering

M. Inui, A. Koura, Y. Kajihara, S. Hosokawa, Ayano Chiba, K. Kimura, F. Shimojo, S. Tsutsui, A. Q.R. Baron

Research output: Contribution to journalArticle

Abstract

Collective dynamics in liquid GeTe was investigated by inelastic x-ray scattering at 2≤Q≤31nm-1. The dynamic structure factor shows clear inelastic excitations. The excitation energies at low Q disperse with increasing Q, consistent with the behavior of a longitudinal-acoustic excitation. The dispersion curve has a flat-topped region around the pseudo-Brillouin-zone boundary, similar to what is observed in liquid Bi [Inui, Phys. Rev. B 92, 054206 (2015)PRBMDO1098-012110.1103/PhysRevB.92.054206]. The dynamic structure factor shows a low-frequency excitation, and its coupling with the longitudinal-acoustic mode plays an important role for a flat-topped dispersion. From these results, it is inferred that atomic dynamics in liquid GeTe is strongly affected by a Peierls distortion similar to liquid Bi. By comparing the momentum transfer dependence of the excitation energy and quasielastic linewidth to partial structure factors obtained by our own ab initio molecular dynamics simulation for liquid GeTe, the quasielastic and inelastic components were found to be correlated with Te-Te and Ge-(Ge,Te) partial structure factors, respectively.

Original languageEnglish
Article number174203
JournalPhysical Review B
Volume97
Issue number17
DOIs
Publication statusPublished - 2018 May 14

Fingerprint

x ray scattering
inelastic scattering
Scattering
X rays
Liquids
liquids
Excitation energy
excitation
acoustic excitation
Momentum transfer
Brillouin zones
Linewidth
momentum transfer
Molecular dynamics
Acoustics
molecular dynamics
low frequencies
acoustics
energy
Computer simulation

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Condensed Matter Physics

Cite this

Peculiar atomic dynamics in liquid GeTe with asymmetrical bonding : Observation by inelastic x-ray scattering. / Inui, M.; Koura, A.; Kajihara, Y.; Hosokawa, S.; Chiba, Ayano; Kimura, K.; Shimojo, F.; Tsutsui, S.; Baron, A. Q.R.

In: Physical Review B, Vol. 97, No. 17, 174203, 14.05.2018.

Research output: Contribution to journalArticle

Inui, M, Koura, A, Kajihara, Y, Hosokawa, S, Chiba, A, Kimura, K, Shimojo, F, Tsutsui, S & Baron, AQR 2018, 'Peculiar atomic dynamics in liquid GeTe with asymmetrical bonding: Observation by inelastic x-ray scattering', Physical Review B, vol. 97, no. 17, 174203. https://doi.org/10.1103/PhysRevB.97.174203
Inui, M. ; Koura, A. ; Kajihara, Y. ; Hosokawa, S. ; Chiba, Ayano ; Kimura, K. ; Shimojo, F. ; Tsutsui, S. ; Baron, A. Q.R. / Peculiar atomic dynamics in liquid GeTe with asymmetrical bonding : Observation by inelastic x-ray scattering. In: Physical Review B. 2018 ; Vol. 97, No. 17.
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