Peculiar sandwich-like π-π interaction regulating the nonplanarity of the model heme crystals

Yoshiki Ohgo; Akito Hoshino; Hidehiro Uekusa; Mikio Nakamura

doi:10.1016/j.inoche.2006.07.024

Peculiar sandwich-like π-π interaction regulating the nonplanarity of the model heme crystals

Yoshiki Ohgo, Akito Hoshino, Hidehiro Uekusa, Mikio Nakamura

Department of Radiology

Research output: Contribution to journal › Article

5 Citations (Scopus)

Abstract

X-ray crystallographic analysis of bis(pyridine N-oxide) complexes of iron(III) porphyrinates has revealed that the two pyridine rings of the axial ligands correctly sandwich the porphyrin ring to induce the deformation of commonly observed S₄ saddled porphyrin ring.

Original language	English
Pages (from-to)	1183-1186
Number of pages	4
Journal	Inorganic Chemistry Communications
Volume	9
Issue number	12
DOIs	https://doi.org/10.1016/j.inoche.2006.07.024
Publication status	Published - 2006 Dec 1

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Keywords

Deformed porphyrin
Hemeprotein
Iron(III)
π-π interaction

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

Cite this

Ohgo, Y., Hoshino, A., Uekusa, H., & Nakamura, M. (2006). Peculiar sandwich-like π-π interaction regulating the nonplanarity of the model heme crystals. Inorganic Chemistry Communications, 9(12), 1183-1186. https://doi.org/10.1016/j.inoche.2006.07.024

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Access to Document

10.1016/j.inoche.2006.07.024