Abstract
X-ray crystallographic analysis of bis(pyridine N-oxide) complexes of iron(III) porphyrinates has revealed that the two pyridine rings of the axial ligands correctly sandwich the porphyrin ring to induce the deformation of commonly observed S4 saddled porphyrin ring.
| Original language | English |
|---|---|
| Pages (from-to) | 1183-1186 |
| Number of pages | 4 |
| Journal | Inorganic Chemistry Communications |
| Volume | 9 |
| Issue number | 12 |
| DOIs | |
| Publication status | Published - 2006 Dec |
| Externally published | Yes |
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Keywords
- π-π interaction
- Deformed porphyrin
- Hemeprotein
- Iron(III)
ASJC Scopus subject areas
- Biochemistry
- Inorganic Chemistry
- Physical and Theoretical Chemistry
- Materials Chemistry
Cite this
Peculiar sandwich-like π-π interaction regulating the nonplanarity of the model heme crystals. / Ohgo, Yoshiki; Hoshino, Akito; Uekusa, Hidehiro; Nakamura, Mikio.
In: Inorganic Chemistry Communications, Vol. 9, No. 12, 12.2006, p. 1183-1186.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Peculiar sandwich-like π-π interaction regulating the nonplanarity of the model heme crystals
AU - Ohgo, Yoshiki
AU - Hoshino, Akito
AU - Uekusa, Hidehiro
AU - Nakamura, Mikio
PY - 2006/12
Y1 - 2006/12
N2 - X-ray crystallographic analysis of bis(pyridine N-oxide) complexes of iron(III) porphyrinates has revealed that the two pyridine rings of the axial ligands correctly sandwich the porphyrin ring to induce the deformation of commonly observed S4 saddled porphyrin ring.
AB - X-ray crystallographic analysis of bis(pyridine N-oxide) complexes of iron(III) porphyrinates has revealed that the two pyridine rings of the axial ligands correctly sandwich the porphyrin ring to induce the deformation of commonly observed S4 saddled porphyrin ring.
KW - π-π interaction
KW - Deformed porphyrin
KW - Hemeprotein
KW - Iron(III)
UR - http://www.scopus.com/inward/record.url?scp=33750930662&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=33750930662&partnerID=8YFLogxK
U2 - 10.1016/j.inoche.2006.07.024
DO - 10.1016/j.inoche.2006.07.024
M3 - Article
AN - SCOPUS:33750930662
VL - 9
SP - 1183
EP - 1186
JO - Inorganic Chemistry Communication
JF - Inorganic Chemistry Communication
SN - 1387-7003
IS - 12
ER -