Peculiar sandwich-like π-π interaction regulating the nonplanarity of the model heme crystals

Yoshiki Ohgo, Akito Hoshino, Hidehiro Uekusa, Mikio Nakamura

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

X-ray crystallographic analysis of bis(pyridine N-oxide) complexes of iron(III) porphyrinates has revealed that the two pyridine rings of the axial ligands correctly sandwich the porphyrin ring to induce the deformation of commonly observed S4 saddled porphyrin ring.

Original languageEnglish
Pages (from-to)1183-1186
Number of pages4
JournalInorganic Chemistry Communications
Volume9
Issue number12
DOIs
Publication statusPublished - 2006 Dec
Externally publishedYes

Fingerprint

Porphyrins
Heme
Pyridine
porphyrins
Crystals
rings
pyridines
crystals
Iron
Ligands
X-Rays
interactions
X rays
Oxides
iron
ligands
oxides
x rays
pyridine N-oxide
pyridine

Keywords

  • π-π interaction
  • Deformed porphyrin
  • Hemeprotein
  • Iron(III)

ASJC Scopus subject areas

  • Biochemistry
  • Inorganic Chemistry
  • Physical and Theoretical Chemistry
  • Materials Chemistry

Cite this

Peculiar sandwich-like π-π interaction regulating the nonplanarity of the model heme crystals. / Ohgo, Yoshiki; Hoshino, Akito; Uekusa, Hidehiro; Nakamura, Mikio.

In: Inorganic Chemistry Communications, Vol. 9, No. 12, 12.2006, p. 1183-1186.

Research output: Contribution to journalArticle

Ohgo, Yoshiki ; Hoshino, Akito ; Uekusa, Hidehiro ; Nakamura, Mikio. / Peculiar sandwich-like π-π interaction regulating the nonplanarity of the model heme crystals. In: Inorganic Chemistry Communications. 2006 ; Vol. 9, No. 12. pp. 1183-1186.
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