Phase equilibrium for structure II clathrate hydrates formed with (fluoromethane + propan-2-ol, 2-methyl-2-propanol, or 2-propanone)

Masatoshi Imai, Yuya Oto, Shinnosuke Nitta, Satoshi Takeya, Ryo Ohmura

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

This paper presents phase-equilibrium pressure-temperature data for the clathrate hydrates formed in the three component systems each consisting of a hydrate-forming gas, a water-soluble freezing-point depression material, and water. These systems are {fluoromethane (CH 3F) + propan-2-ol + water}, (fluoromethane + 2-methyl-2-propanol + water), and (fluoromethane + 2-propanone + water). The mole ratio of water and the water-soluble material (papan-2-ol, 2-methyl-2-propanol, or 2-propanone) was 17:1. The temperature range over which the phase-equilibrium measurements were performed extended to 267.6 K on the lower side and 295.8 K on the higher side. The phase-equilibrium pressures in these three systems were found to be lower than that in the binary (fluoromethane + water) system at a given system temperature. The crystallographic structure of the hydrates formed in the systems with 2-methyl-2-propanol and 2-propanone was determined to be structure II based on the powder X-ray diffraction measurements.

Original languageEnglish
Pages (from-to)17-20
Number of pages4
JournalJournal of Chemical Thermodynamics
Volume47
DOIs
Publication statusPublished - 2012 Apr

Fingerprint

2-Propanol
clathrates
Propanol
Acetone
Hydrates
Phase equilibria
hydrates
Water
water
fluoromethane
Freezing
X ray powder diffraction
Temperature
melting points
temperature
Gases
methylidyne
diffraction
gases

Keywords

  • Clathrate hydrates
  • Gas hydrates
  • Hydrate heat pump
  • Phase equilibria

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Atomic and Molecular Physics, and Optics
  • Materials Science(all)

Cite this

Phase equilibrium for structure II clathrate hydrates formed with (fluoromethane + propan-2-ol, 2-methyl-2-propanol, or 2-propanone). / Imai, Masatoshi; Oto, Yuya; Nitta, Shinnosuke; Takeya, Satoshi; Ohmura, Ryo.

In: Journal of Chemical Thermodynamics, Vol. 47, 04.2012, p. 17-20.

Research output: Contribution to journalArticle

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AB - This paper presents phase-equilibrium pressure-temperature data for the clathrate hydrates formed in the three component systems each consisting of a hydrate-forming gas, a water-soluble freezing-point depression material, and water. These systems are {fluoromethane (CH 3F) + propan-2-ol + water}, (fluoromethane + 2-methyl-2-propanol + water), and (fluoromethane + 2-propanone + water). The mole ratio of water and the water-soluble material (papan-2-ol, 2-methyl-2-propanol, or 2-propanone) was 17:1. The temperature range over which the phase-equilibrium measurements were performed extended to 267.6 K on the lower side and 295.8 K on the higher side. The phase-equilibrium pressures in these three systems were found to be lower than that in the binary (fluoromethane + water) system at a given system temperature. The crystallographic structure of the hydrates formed in the systems with 2-methyl-2-propanol and 2-propanone was determined to be structure II based on the powder X-ray diffraction measurements.

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