Phase equilibrium for structure II hydrates formed with krypton co-existing with cyclopentane, cyclopentene, or tetrahydropyran

Satoshi Takeya, Ryo Ohmura

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Abstract

This paper reports the pressure-temperature conditions for the vapor + liquid + liquid + hydrate four-phase equilibrium in the systems of krypton and water plus each of the following substances: cyclopentane, cyclopentene, and tetrahydropyran. The pressure ranges of the present measurements in the three systems are (0.116 to 7.664) MPa at temperatures from (283.8 to 308.5) K in the cyclopentane system, (0.121 to 2.047) MPa at temperatures from (280.2 to 297.1) K in the cyclopentene system, and (0.118 to 2.075) MPa at temperatures from (278.8 to 296.7) K in the tetrahydropyran system. These equilibrium pressures are lower by at least 4 MPa than those in the binary krypton + water system. The crystallographic structures of the hydrates are identified to be structure II based on the powder X-ray diffraction measurements.

Original languageEnglish
Pages (from-to)1880-1883
Number of pages4
JournalJournal of Chemical and Engineering Data
Volume51
Issue number5
DOIs
Publication statusPublished - 2006 Sep 1

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ASJC Scopus subject areas

  • Chemistry(all)
  • Chemical Engineering(all)

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