Phenyltrichlorogermane synthesis by the reaction of chlorobenzene and the dichlorogermylene intermediate formed from elemental germanium and tetrachlorogermane

Masaki Okamoto, Takuya Asano, Eiichi Suzuki

Research output: Contribution to journalArticle

9 Citations (Scopus)

Abstract

Phenyltrichlorogermane was synthesized with high selectivity, 96%, from elemental germanium, tetrachlorogermane, and chlorobenzene using no catalyst, almost all germanium and tetrachlorogermane being converted. Dichlorogermylene was formed as a reaction intermediate by the reaction of germanium with tetrachlorogermane and inserted into the C-Cl bond of chlorobenzene to yield phenyltrichlorogermane.

Original languageEnglish
Pages (from-to)5583-5585
Number of pages3
JournalOrganometallics
Volume20
Issue number26
DOIs
Publication statusPublished - 2001 Dec 24
Externally publishedYes

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Germanium
chlorobenzenes
germanium
synthesis
Reaction intermediates
reaction intermediates
selectivity
catalysts
Catalysts
chlorobenzene

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

Cite this

Phenyltrichlorogermane synthesis by the reaction of chlorobenzene and the dichlorogermylene intermediate formed from elemental germanium and tetrachlorogermane. / Okamoto, Masaki; Asano, Takuya; Suzuki, Eiichi.

In: Organometallics, Vol. 20, No. 26, 24.12.2001, p. 5583-5585.

Research output: Contribution to journalArticle

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