Phosphoric acid bridged cobalt bis(dicarbollide) ion as a highly efficient catalyst for the organocatalytic hydrogenation of ketimines

Takahiko Akiyama, Kodai Saito, Slawomir Janczak, Zbigniew J. Lesnikowski

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

The high-yield reduction of aromatic ketimines into amines by using a novel catalyst based on a metallacarborane structure, 8,8′-μ-phosphate[(1,2- dicarba-closo-undecaborane)-3,3′-cobalt(-1)(1′,2′-dicarba- closo-undecaborane)] acid, is described.

Original languageEnglish
Article numberST-2013-D1176-L
Pages (from-to)795-798
Number of pages4
JournalSynlett
Volume25
Issue number6
DOIs
Publication statusPublished - 2014
Externally publishedYes

Fingerprint

Cobalt
Hydrogenation
Amines
Phosphates
Ions
Catalysts
Acids
phosphoric acid
ketimine

Keywords

  • amines
  • catalysis
  • hydrogenation
  • imines
  • metallacarboranes
  • reduction

ASJC Scopus subject areas

  • Organic Chemistry

Cite this

Phosphoric acid bridged cobalt bis(dicarbollide) ion as a highly efficient catalyst for the organocatalytic hydrogenation of ketimines. / Akiyama, Takahiko; Saito, Kodai; Janczak, Slawomir; Lesnikowski, Zbigniew J.

In: Synlett, Vol. 25, No. 6, ST-2013-D1176-L, 2014, p. 795-798.

Research output: Contribution to journalArticle

Akiyama, Takahiko ; Saito, Kodai ; Janczak, Slawomir ; Lesnikowski, Zbigniew J. / Phosphoric acid bridged cobalt bis(dicarbollide) ion as a highly efficient catalyst for the organocatalytic hydrogenation of ketimines. In: Synlett. 2014 ; Vol. 25, No. 6. pp. 795-798.
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