Phosphoric acid bridged cobalt bis(dicarbollide) ion as a highly efficient catalyst for the organocatalytic hydrogenation of ketimines

Takahiko Akiyama; Kodai Saito; Slawomir Janczak; Zbigniew J. Lesnikowski

doi:10.1055/s-0033-1340847

Phosphoric acid bridged cobalt bis(dicarbollide) ion as a highly efficient catalyst for the organocatalytic hydrogenation of ketimines

Takahiko Akiyama, Kodai Saito, Slawomir Janczak, Zbigniew J. Lesnikowski

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

The high-yield reduction of aromatic ketimines into amines by using a novel catalyst based on a metallacarborane structure, 8,8′-μ-phosphate[(1,2- dicarba-closo-undecaborane)-3,3′-cobalt(-1)(1′,2′-dicarba- closo-undecaborane)] acid, is described.

Original language	English
Article number	ST-2013-D1176-L
Pages (from-to)	795-798
Number of pages	4
Journal	Synlett
Volume	25
Issue number	6
DOIs	https://doi.org/10.1055/s-0033-1340847
Publication status	Published - 2014 Apr
Externally published	Yes

Keywords

amines
catalysis
hydrogenation
imines
metallacarboranes
reduction

ASJC Scopus subject areas

Organic Chemistry

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AU - Akiyama, Takahiko

AU - Saito, Kodai

AU - Janczak, Slawomir

AU - Lesnikowski, Zbigniew J.

PY - 2014/4

Y1 - 2014/4

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AB - The high-yield reduction of aromatic ketimines into amines by using a novel catalyst based on a metallacarborane structure, 8,8′-μ-phosphate[(1,2- dicarba-closo-undecaborane)-3,3′-cobalt(-1)(1′,2′-dicarba- closo-undecaborane)] acid, is described.

KW - amines

KW - catalysis

KW - hydrogenation

KW - imines

KW - metallacarboranes

KW - reduction

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Phosphoric acid bridged cobalt bis(dicarbollide) ion as a highly efficient catalyst for the organocatalytic hydrogenation of ketimines

Abstract

Keywords

ASJC Scopus subject areas

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