Phosphoric acid bridged cobalt bis(dicarbollide) ion as a highly efficient catalyst for the organocatalytic hydrogenation of ketimines

Takahiko Akiyama, Kodai Saito, Slawomir Janczak, Zbigniew J. Lesnikowski

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

The high-yield reduction of aromatic ketimines into amines by using a novel catalyst based on a metallacarborane structure, 8,8′-μ-phosphate[(1,2- dicarba-closo-undecaborane)-3,3′-cobalt(-1)(1′,2′-dicarba- closo-undecaborane)] acid, is described.

Original languageEnglish
Article numberST-2013-D1176-L
Pages (from-to)795-798
Number of pages4
JournalSynlett
Volume25
Issue number6
DOIs
Publication statusPublished - 2014 Apr

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Keywords

  • amines
  • catalysis
  • hydrogenation
  • imines
  • metallacarboranes
  • reduction

ASJC Scopus subject areas

  • Organic Chemistry

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