Abstract
Photo-induced glycosylations of several acceptors with trichloroacetimidate donors using bis(2-naphthyl)disulfide as an organo-Lewis photoacid (LPA) catalyst proceeded effectively to give the corresponding glycosides in good to high yields. In addition, the ground and excited state absorption spectra of bis(2-naphthyl)disulfide with or without NEt3 suggested the Lewis acidity of bis(2-naphthyl)disulfide upon photo-irradiation.
| Original language | English |
|---|---|
| Pages (from-to) | 851-855 |
| Number of pages | 5 |
| Journal | Organic and Biomolecular Chemistry |
| Volume | 18 |
| Issue number | 5 |
| DOIs | |
| Publication status | Published - 2020 Jan 1 |
ASJC Scopus subject areas
- Biochemistry
- Physical and Theoretical Chemistry
- Organic Chemistry
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Cite this
Iibuchi, N., Eto, T., Aoyagi, M., Kurinami, R., Sakai, H., Hasobe, T., Takahashi, D., & Toshima, K. (2020). Photo-induced glycosylation using a diaryldisulfide as an organo-Lewis photoacid catalyst. Organic and Biomolecular Chemistry, 18(5), 851-855. https://doi.org/10.1039/c9ob02674f