Photo-induced glycosylation using a diaryldisulfide as an organo-Lewis photoacid catalyst

Naoto Iibuchi; Takahiro Eto; Manabu Aoyagi; Reiji Kurinami; Hayato Sakai; Taku Hasobe; Daisuke Takahashi; Kazunobu Toshima

doi:10.1039/c9ob02674f

Photo-induced glycosylation using a diaryldisulfide as an organo-Lewis photoacid catalyst

Naoto Iibuchi, Takahiro Eto, Manabu Aoyagi, Reiji Kurinami, Hayato Sakai, Taku Hasobe, Daisuke Takahashi, Kazunobu Toshima

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

Photo-induced glycosylations of several acceptors with trichloroacetimidate donors using bis(2-naphthyl)disulfide as an organo-Lewis photoacid (LPA) catalyst proceeded effectively to give the corresponding glycosides in good to high yields. In addition, the ground and excited state absorption spectra of bis(2-naphthyl)disulfide with or without NEt₃ suggested the Lewis acidity of bis(2-naphthyl)disulfide upon photo-irradiation.

Original language	English
Pages (from-to)	851-855
Number of pages	5
Journal	Organic and Biomolecular Chemistry
Volume	18
Issue number	5
DOIs	https://doi.org/10.1039/c9ob02674f
Publication status	Published - 2020 Jan 1

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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Photo-induced glycosylation using a diaryldisulfide as an organo-Lewis photoacid catalyst. / Iibuchi, Naoto; Eto, Takahiro; Aoyagi, Manabu; Kurinami, Reiji; Sakai, Hayato ; Hasobe, Taku ; Takahashi, Daisuke ; Toshima, Kazunobu.

In: Organic and Biomolecular Chemistry, Vol. 18, No. 5, 01.01.2020, p. 851-855.

Research output: Contribution to journal › Article › peer-review

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AU - Sakai, Hayato

AU - Hasobe, Taku

AU - Takahashi, Daisuke

AU - Toshima, Kazunobu

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