Photocarrier dynamics in CIGS, CZTS, and related materials revealed by ultrafast optical spectroscopy

Makoto Okano, Le Quang Phuong, Yoshihiko Kanemitsu

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

We discuss the photocarrier dynamics in emerging thin-film solar-cell materials, Cu(In,Ga)Se<inf>2</inf> (CIGS), Cu<inf>2</inf>ZnSnS<inf>4</inf> (CZTS), and CdTe-based nanocrystals (NCs), using time-resolved photoluminescence and femtosecond pump-probe spectroscopy. In CIGS and CZTS samples, we found long-lived free photocarriers and slow intraband relaxation at room temperature. These distinctive behaviors of the free carriers are considered common features in multinary semiconductors and are related to the complicated near-band edge structure due to potential fluctuations, which might affect solar-cell efficiencies. We revealed the relationship in CdTe-based type-II NCs between hot carrier transfer and intraband relaxation, providing a better understanding of the charge separation mechanism in multinary semiconductors. We also demonstrated the usefulness of ultra-fast optical spectroscopy techniques for clarifying the photocarrier dynamics in various semiconducting bulk and nano-structure materials for solar cells.

Original languageEnglish
Pages (from-to)1219-1224
Number of pages6
JournalPhysica Status Solidi (B) Basic Research
Volume252
Issue number6
DOIs
Publication statusPublished - 2015 Jun 1
Externally publishedYes

Fingerprint

Nanocrystals
Solar cells
solar cells
Semiconductor materials
Hot carriers
nanocrystals
spectroscopy
Photoluminescence
Pumps
Spectroscopy
polarization (charge separation)
emerging
pumps
photoluminescence
probes
room temperature
thin films
Temperature
Optical spectroscopy
Thin film solar cells

Keywords

  • Carrier dynamics
  • Multinary semiconductors
  • Optical properties
  • Solar cells

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Electronic, Optical and Magnetic Materials

Cite this

Photocarrier dynamics in CIGS, CZTS, and related materials revealed by ultrafast optical spectroscopy. / Okano, Makoto; Phuong, Le Quang; Kanemitsu, Yoshihiko.

In: Physica Status Solidi (B) Basic Research, Vol. 252, No. 6, 01.06.2015, p. 1219-1224.

Research output: Contribution to journalArticle

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