Clusters of Mg+ with AN molecules, Mg(AN)n+, were investigated by photodissociation spectroscopy and theoretical calculations. In the dissociation spectrum of n=1, two absorption bands were observed at 26 400 and 40 800 cm-1. On the other hand, three absorption bands centered at 22 600, 28 800, and 37 500 cm-1 appeared for n=2. These absorption bands were assigned by using DFT(B3LYP/6-31+G*) and CIS/6-31+G* methods.
ASJC Scopus subject areas
- Physics and Astronomy(all)
- Physical and Theoretical Chemistry