### Abstract

Clusters of Mg^{+} with AN molecules, Mg(AN)_{n}^{+}, were investigated by photodissociation spectroscopy and theoretical calculations. In the dissociation spectrum of n=1, two absorption bands were observed at 26 400 and 40 800 cm^{-1}. On the other hand, three absorption bands centered at 22 600, 28 800, and 37 500 cm^{-1} appeared for n=2. These absorption bands were assigned by using DFT(B3LYP/6-31+G*) and CIS/6-31+G* methods.

Original language | English |
---|---|

Pages (from-to) | 5456-5464 |

Number of pages | 9 |

Journal | Journal of Chemical Physics |

Volume | 118 |

Issue number | 12 |

DOIs | |

Publication status | Published - 2003 Mar 22 |

Externally published | Yes |

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### ASJC Scopus subject areas

- Atomic and Molecular Physics, and Optics

### Cite this

_{2}=CHCN)

_{n}

^{+}: Excited electronic states of n = 1 and 2 and intracluster electron transfer for n = 3 and 4.

*Journal of Chemical Physics*,

*118*(12), 5456-5464. https://doi.org/10.1063/1.1541020

**Photodissociation of Mg(CH _{2}=CHCN)_{n}^{+} : Excited electronic states of n = 1 and 2 and intracluster electron transfer for n = 3 and 4.** / Furuya, Ari; Ohshimo, Keijiro; Tsunoyama, Hironori; Misaizu, Fuminori; Ohno, Koichi; Watanabe, Hidekazu.

Research output: Contribution to journal › Article

_{2}=CHCN)

_{n}

^{+}: Excited electronic states of n = 1 and 2 and intracluster electron transfer for n = 3 and 4',

*Journal of Chemical Physics*, vol. 118, no. 12, pp. 5456-5464. https://doi.org/10.1063/1.1541020

_{2}=CHCN)

_{n}

^{+}: Excited electronic states of n = 1 and 2 and intracluster electron transfer for n = 3 and 4. Journal of Chemical Physics. 2003 Mar 22;118(12):5456-5464. https://doi.org/10.1063/1.1541020

}

TY - JOUR

T1 - Photodissociation of Mg(CH2=CHCN)n+

T2 - Excited electronic states of n = 1 and 2 and intracluster electron transfer for n = 3 and 4

AU - Furuya, Ari

AU - Ohshimo, Keijiro

AU - Tsunoyama, Hironori

AU - Misaizu, Fuminori

AU - Ohno, Koichi

AU - Watanabe, Hidekazu

PY - 2003/3/22

Y1 - 2003/3/22

N2 - Clusters of Mg+ with AN molecules, Mg(AN)n+, were investigated by photodissociation spectroscopy and theoretical calculations. In the dissociation spectrum of n=1, two absorption bands were observed at 26 400 and 40 800 cm-1. On the other hand, three absorption bands centered at 22 600, 28 800, and 37 500 cm-1 appeared for n=2. These absorption bands were assigned by using DFT(B3LYP/6-31+G*) and CIS/6-31+G* methods.

AB - Clusters of Mg+ with AN molecules, Mg(AN)n+, were investigated by photodissociation spectroscopy and theoretical calculations. In the dissociation spectrum of n=1, two absorption bands were observed at 26 400 and 40 800 cm-1. On the other hand, three absorption bands centered at 22 600, 28 800, and 37 500 cm-1 appeared for n=2. These absorption bands were assigned by using DFT(B3LYP/6-31+G*) and CIS/6-31+G* methods.

UR - http://www.scopus.com/inward/record.url?scp=0037461017&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0037461017&partnerID=8YFLogxK

U2 - 10.1063/1.1541020

DO - 10.1063/1.1541020

M3 - Article

VL - 118

SP - 5456

EP - 5464

JO - Journal of Chemical Physics

JF - Journal of Chemical Physics

SN - 0021-9606

IS - 12

ER -