Photodissociation of Mg(CH2=CHCN)n+: Excited electronic states of n = 1 and 2 and intracluster electron transfer for n = 3 and 4

Ari Furuya, Keijiro Ohshimo, Hironori Tsunoyama, Fuminori Misaizu, Koichi Ohno, Hidekazu Watanabe

Research output: Contribution to journalArticlepeer-review

8 Citations (Scopus)

Abstract

Clusters of Mg+ with AN molecules, Mg(AN)n+, were investigated by photodissociation spectroscopy and theoretical calculations. In the dissociation spectrum of n=1, two absorption bands were observed at 26 400 and 40 800 cm-1. On the other hand, three absorption bands centered at 22 600, 28 800, and 37 500 cm-1 appeared for n=2. These absorption bands were assigned by using DFT(B3LYP/6-31+G*) and CIS/6-31+G* methods.

Original languageEnglish
Pages (from-to)5456-5464
Number of pages9
JournalJournal of Chemical Physics
Volume118
Issue number12
DOIs
Publication statusPublished - 2003 Mar 22
Externally publishedYes

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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