TY - JOUR
T1 - Photoelectron spectroscopy and mass distributions of aluminum-sulfur cluster anions (AlnSm-)
AU - Nakajima, Atsushi
AU - Zhang, Nan
AU - Kawamata, Hiroshi
AU - Hayase, Takasuke
AU - Nakao, Kojiro
AU - Kaya, Koji
N1 - Funding Information:
work was partly supported by a Grant-in-Aid for Scientific Research on Priority Areas from the Ministry of Education, Science and Culture.
PY - 1995/7/28
Y1 - 1995/7/28
N2 - Photoelectron spectra of AlnSm- cluster anions (0 ≤ n, m ≤ 10) were measured at photon energies of 3.49 and 4.66 eV, by using a magnetic bottle electron spectrometer. The AlnSm-. clusters were produced by laser vaporization of an aluminum-sulfur mixed rod in He carrier gas. The abundant AInSM clusters are three types of AlS-(Al2S3)k, AlS2-(Al2S3)k, and (Al2S3)k-, where an unit of Al2S3 aggregates with ion cores of AlS-, AlS2-, and Al2S3, respectively. Al3S3 is exceptionally stable with its geometrical structure.
AB - Photoelectron spectra of AlnSm- cluster anions (0 ≤ n, m ≤ 10) were measured at photon energies of 3.49 and 4.66 eV, by using a magnetic bottle electron spectrometer. The AlnSm-. clusters were produced by laser vaporization of an aluminum-sulfur mixed rod in He carrier gas. The abundant AInSM clusters are three types of AlS-(Al2S3)k, AlS2-(Al2S3)k, and (Al2S3)k-, where an unit of Al2S3 aggregates with ion cores of AlS-, AlS2-, and Al2S3, respectively. Al3S3 is exceptionally stable with its geometrical structure.
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U2 - 10.1016/0009-2614(95)00653-L
DO - 10.1016/0009-2614(95)00653-L
M3 - Article
AN - SCOPUS:0000214835
SN - 0009-2614
VL - 241
SP - 295
EP - 300
JO - Chemical Physics Letters
JF - Chemical Physics Letters
IS - 4
ER -