Photoelectron spectroscopy of bimetallic aluminum cobalt cluster anions: Comparison of electronic structure and hydrogen chemisorption rates

Axel Pramann, Atsushi Nakajima, Koji Kaya

Research output: Contribution to journalArticle

26 Citations (Scopus)

Abstract

Photoelectron spectroscopy (PES) of mass-selected Al-rich AlnCo- and Co-rich ConAlm- clusters was performed using 3.49 eV photon energy. Electronic structures of both cluster series were studied under the same experimental conditions. Electron affinities and vertical detachment energies were measured. The resulting data was analyzed in detail.

Original languageEnglish
Pages (from-to)5404-5410
Number of pages7
JournalJournal of Chemical Physics
Volume115
Issue number12
DOIs
Publication statusPublished - 2001 Sep 22

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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