Photoelectron spectroscopy of (C6F6)- n and (Au-C6F6)- clusters

A. Nakajima, T. Taguwa, K. Hoshino, T. Sugioka, T. Naganuma, F. Oho, K. Watanabe, K. Nakao, Y. Konishi, R. Kishi, K. Kaya

Research output: Contribution to journalArticle

105 Citations (Scopus)

Abstract

Photoelectron spectra of hexafluorobenzene (C6F6) cluster anions and its Au complex anion were measured in the gas phase at the photon energy of 3.49 eV, using a magnetic bottle electron spectrometer having ≈ 80 meV resolution. The spectra show unresolved broad features: The vertical detachment energies (VDEs) were determined from the maxima of the spectra. The VDE of (C6F6)- n gradually increases by 0.1-0.2 eV with the cluster size (n=1-8) from 1.56(3) to 2.54(6) eV, and the VDE of (Au-C6F6)- anion is 1.99(5) eV.

Original languageEnglish
Pages (from-to)22-26
Number of pages5
JournalChemical Physics Letters
Volume214
Issue number1
DOIs
Publication statusPublished - 1993 Oct 22
Externally publishedYes

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

Fingerprint Dive into the research topics of 'Photoelectron spectroscopy of (C<sub>6</sub>F<sub>6</sub>)<sup>-</sup> <sub>n</sub> and (Au-C<sub>6</sub>F<sub>6</sub>)<sup>-</sup> clusters'. Together they form a unique fingerprint.

  • Cite this

    Nakajima, A., Taguwa, T., Hoshino, K., Sugioka, T., Naganuma, T., Oho, F., Watanabe, K., Nakao, K., Konishi, Y., Kishi, R., & Kaya, K. (1993). Photoelectron spectroscopy of (C6F6)- n and (Au-C6F6)- clusters. Chemical Physics Letters, 214(1), 22-26. https://doi.org/10.1016/0009-2614(93)85449-X