Photoreduction of prussian blue intercalated into titania nanosheet ultrathin films

Takashi Yamamoto, Naoki Saso, Yasushi Umemura, Yasuaki Einaga

Research output: Contribution to journalArticle

33 Citations (Scopus)

Abstract

(Graph Presented) Ultrathin fims composed of titania nanosheets and Prussian Blue were prepared by using the modified Langmuir-Blodgett technique. The ultrathin films could be deposited in a layer-by-layer manner with lamellar structure. Upon band gap excitation of titania nanosheets, the generated electrons were injected into ferromagnetic Prussian Blue, resulting in reduction to paramagnetic Prussian White. It was revealed that the reaction could proceed only in the presence of hole-scavenging interlayer water molecules.

Original languageEnglish
Pages (from-to)13196-13197
Number of pages2
JournalJournal of the American Chemical Society
Volume131
Issue number37
DOIs
Publication statusPublished - 2009 Sep 23

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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