Photoresponsive liquid-crystalline polymers containing a block mesogenic side chain: Systematic studies on structural parameters for nanophase-separated structures

Kunihiko Okano, Yasuyuki Mikami, Mai Hidaka, Takashi Yamashita

Research output: Contribution to journalArticle

10 Citations (Scopus)

Abstract

A family of liquid-crystalline polymers (LCPs) containing a block mesogenic side group was synthesized by varying the hydrophilic moiety (oligooxyethylene) ratio. As the oligooxyethylene content increased, the range of the LC phase narrowed or vanished. The polymers were subjected to annealing and exposed on the surface of films, and their morphologies were observed using an atomic force microscope. While the annealed films prepared from the LCPs showed nanophase separation on the surface, the film of the amorphous polymer exhibited no phase separation. Under the optimized conditions, two types of irradiation procedures were adopted: (i) UV (365 nm) light illumination for a phase transition induced by trans-cis photoisomerization and (ii) linearly polarized visible (>436 nm) illumination for a photoinduced alignment change. These results revealed that the photoresponsive behavior of the nanostructure is strongly coupled to the molecular alignments induced by annealing.

Original languageEnglish
Pages (from-to)5605-5611
Number of pages7
JournalMacromolecules
Volume44
Issue number14
DOIs
Publication statusPublished - 2011 Jul 26

Fingerprint

Liquid crystal polymers
Polymers
Lighting
Annealing
Photoisomerization
Molecular orientation
Phase separation
Nanostructures
Microscopes
Phase transitions
Irradiation

ASJC Scopus subject areas

  • Organic Chemistry
  • Materials Chemistry
  • Polymers and Plastics
  • Inorganic Chemistry

Cite this

Photoresponsive liquid-crystalline polymers containing a block mesogenic side chain : Systematic studies on structural parameters for nanophase-separated structures. / Okano, Kunihiko; Mikami, Yasuyuki; Hidaka, Mai; Yamashita, Takashi.

In: Macromolecules, Vol. 44, No. 14, 26.07.2011, p. 5605-5611.

Research output: Contribution to journalArticle

Okano, Kunihiko ; Mikami, Yasuyuki ; Hidaka, Mai ; Yamashita, Takashi. / Photoresponsive liquid-crystalline polymers containing a block mesogenic side chain : Systematic studies on structural parameters for nanophase-separated structures. In: Macromolecules. 2011 ; Vol. 44, No. 14. pp. 5605-5611.
@article{7107b2fbd781488f901a0ea0bc6070b2,
title = "Photoresponsive liquid-crystalline polymers containing a block mesogenic side chain: Systematic studies on structural parameters for nanophase-separated structures",
abstract = "A family of liquid-crystalline polymers (LCPs) containing a block mesogenic side group was synthesized by varying the hydrophilic moiety (oligooxyethylene) ratio. As the oligooxyethylene content increased, the range of the LC phase narrowed or vanished. The polymers were subjected to annealing and exposed on the surface of films, and their morphologies were observed using an atomic force microscope. While the annealed films prepared from the LCPs showed nanophase separation on the surface, the film of the amorphous polymer exhibited no phase separation. Under the optimized conditions, two types of irradiation procedures were adopted: (i) UV (365 nm) light illumination for a phase transition induced by trans-cis photoisomerization and (ii) linearly polarized visible (>436 nm) illumination for a photoinduced alignment change. These results revealed that the photoresponsive behavior of the nanostructure is strongly coupled to the molecular alignments induced by annealing.",
author = "Kunihiko Okano and Yasuyuki Mikami and Mai Hidaka and Takashi Yamashita",
year = "2011",
month = "7",
day = "26",
doi = "10.1021/ma200558t",
language = "English",
volume = "44",
pages = "5605--5611",
journal = "Macromolecules",
issn = "0024-9297",
publisher = "American Chemical Society",
number = "14",

}

TY - JOUR

T1 - Photoresponsive liquid-crystalline polymers containing a block mesogenic side chain

T2 - Systematic studies on structural parameters for nanophase-separated structures

AU - Okano, Kunihiko

AU - Mikami, Yasuyuki

AU - Hidaka, Mai

AU - Yamashita, Takashi

PY - 2011/7/26

Y1 - 2011/7/26

N2 - A family of liquid-crystalline polymers (LCPs) containing a block mesogenic side group was synthesized by varying the hydrophilic moiety (oligooxyethylene) ratio. As the oligooxyethylene content increased, the range of the LC phase narrowed or vanished. The polymers were subjected to annealing and exposed on the surface of films, and their morphologies were observed using an atomic force microscope. While the annealed films prepared from the LCPs showed nanophase separation on the surface, the film of the amorphous polymer exhibited no phase separation. Under the optimized conditions, two types of irradiation procedures were adopted: (i) UV (365 nm) light illumination for a phase transition induced by trans-cis photoisomerization and (ii) linearly polarized visible (>436 nm) illumination for a photoinduced alignment change. These results revealed that the photoresponsive behavior of the nanostructure is strongly coupled to the molecular alignments induced by annealing.

AB - A family of liquid-crystalline polymers (LCPs) containing a block mesogenic side group was synthesized by varying the hydrophilic moiety (oligooxyethylene) ratio. As the oligooxyethylene content increased, the range of the LC phase narrowed or vanished. The polymers were subjected to annealing and exposed on the surface of films, and their morphologies were observed using an atomic force microscope. While the annealed films prepared from the LCPs showed nanophase separation on the surface, the film of the amorphous polymer exhibited no phase separation. Under the optimized conditions, two types of irradiation procedures were adopted: (i) UV (365 nm) light illumination for a phase transition induced by trans-cis photoisomerization and (ii) linearly polarized visible (>436 nm) illumination for a photoinduced alignment change. These results revealed that the photoresponsive behavior of the nanostructure is strongly coupled to the molecular alignments induced by annealing.

UR - http://www.scopus.com/inward/record.url?scp=79960498822&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=79960498822&partnerID=8YFLogxK

U2 - 10.1021/ma200558t

DO - 10.1021/ma200558t

M3 - Article

AN - SCOPUS:79960498822

VL - 44

SP - 5605

EP - 5611

JO - Macromolecules

JF - Macromolecules

SN - 0024-9297

IS - 14

ER -