Platinum(II)-catalyzed generation and [3+2] cycloaddition reaction of α,β-unsaturated carbene complex intermediates for the preparation of polycyclic compounds

Kodai Saito, Hideyuki Sogou, Takuya Suga, Hiroyuki Kusama, Nobuharu Iwasawa

Research output: Contribution to journalArticlepeer-review

80 Citations (Scopus)

Abstract

Pt(II)-catalyzed generation of unsaturated carbene complex intermediates from various propargyl ether derivatives based on electrophilic activation of alkynes was realized. These in situ generated unsaturated carbene complexes undergo [3+2] cycloaddition reaction with various vinyl ethers, leading to efficient formation of indoles, naphthols, and benzofuran fused with a five-membered ring in high yields.

Original languageEnglish
Pages (from-to)689-691
Number of pages3
JournalJournal of the American Chemical Society
Volume133
Issue number4
DOIs
Publication statusPublished - 2011 Feb 2
Externally publishedYes

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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