We report the optical perturbation of atomic arrangement in the layered in GeTe/Sb2Te3 phase change memory material. To observe the structural change, the coherent A1 mode of GeTe4 local structure was investigated at various polarization angles of femtosecond pump pulses with the fluence at 78 μ J / cm2. p-polarization found to be more effective in inducing the A1 frequency shift that can be either reversible or irreversible depending on the pump fluence. The predominant origin of this shift is attributed to rearrangement of Ge atoms driven by anisotropic dissociation of the Ge-Te bonds along the  axis after the p-polarized pulse irradiation.
ASJC Scopus subject areas
- Physics and Astronomy (miscellaneous)