Poly-L-lysine-induced self-association and luminescence of dicyanoaurate(I)

Toshiyuki Moriuchi; Kazuki Yoshii; Chiaki Katano; Toshikazu Hirao

doi:10.1246/cl.2010.841

Poly-L-lysine-induced self-association and luminescence of dicyanoaurate(I)

Toshiyuki Moriuchi, Kazuki Yoshii, Chiaki Katano, Toshikazu Hirao

Research output: Contribution to journal › Article › peer-review

13 Citations (Scopus)

Abstract

The assembling and self-association of anionic [Au(CN)₂] ^- spatially along cationic β-sheeted poly-L-lysine, P(Lys), through electrostatic interaction was demonstrated to form luminescent [Au(CN)₂]^- aggregates, wherein negatively charged [Au(CN)₂]^- was found to stabilize the β-sheet structure by suppressing repulsion between the positively charged side chains.

Original language	English
Pages (from-to)	841-843
Number of pages	3
Journal	Chemistry Letters
Volume	39
Issue number	8
DOIs	https://doi.org/10.1246/cl.2010.841
Publication status	Published - 2010
Externally published	Yes

ASJC Scopus subject areas

Chemistry(all)

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10.1246/cl.2010.841

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abstract = "The assembling and self-association of anionic [Au(CN)2] - spatially along cationic β-sheeted poly-L-lysine, P(Lys), through electrostatic interaction was demonstrated to form luminescent [Au(CN)2]- aggregates, wherein negatively charged [Au(CN)2]- was found to stabilize the β-sheet structure by suppressing repulsion between the positively charged side chains.",

author = "Toshiyuki Moriuchi and Kazuki Yoshii and Chiaki Katano and Toshikazu Hirao",

year = "2010",

doi = "10.1246/cl.2010.841",

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journal = "Chemistry Letters",

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T1 - Poly-L-lysine-induced self-association and luminescence of dicyanoaurate(I)

AU - Moriuchi, Toshiyuki

AU - Yoshii, Kazuki

AU - Katano, Chiaki

AU - Hirao, Toshikazu

PY - 2010

Y1 - 2010

N2 - The assembling and self-association of anionic [Au(CN)2] - spatially along cationic β-sheeted poly-L-lysine, P(Lys), through electrostatic interaction was demonstrated to form luminescent [Au(CN)2]- aggregates, wherein negatively charged [Au(CN)2]- was found to stabilize the β-sheet structure by suppressing repulsion between the positively charged side chains.

AB - The assembling and self-association of anionic [Au(CN)2] - spatially along cationic β-sheeted poly-L-lysine, P(Lys), through electrostatic interaction was demonstrated to form luminescent [Au(CN)2]- aggregates, wherein negatively charged [Au(CN)2]- was found to stabilize the β-sheet structure by suppressing repulsion between the positively charged side chains.

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Poly-L-lysine-induced self-association and luminescence of dicyanoaurate(I)

Abstract

ASJC Scopus subject areas

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