Poly[[4-(N-tert-butyl-N-hydroxyamino)phenyl]acetylene] and the Magnetic Property of Its Radical Derivative

Hiroyuki Nishide, Takashi Kaneko, Naoki Yoshioka, Haruhisa Akiyama, Masukazu Igarashi, Eishun Tsuchida

Research output: Contribution to journalArticle

38 Citations (Scopus)

Abstract

[4-(N-tert-Butyl-N-hydroxyamino)phenyl]acetylene (7) was synthesized and polymerized to yield a solvent-soluble polyacetylene: poly [[4-(N-tert-butyl-N-hydroxyamino)phenyl] acetylene] (8). Oxidation of the polymer gave its radical derivative: the ESR spectrum showed a broad signal only in the Δm8 = ±1 region, and magnetic measurement with a SQUID magnetometer revealed an antiferromagnetic through-space interaction.

Original languageEnglish
Pages (from-to)4567-4571
Number of pages5
JournalMacromolecules
Volume26
Issue number17
DOIs
Publication statusPublished - 1993 Jan 1
Externally publishedYes

    Fingerprint

ASJC Scopus subject areas

  • Organic Chemistry
  • Polymers and Plastics
  • Inorganic Chemistry
  • Materials Chemistry

Cite this