Polymeric and monomeric forms of a schiff base-nitridomanganese(V) complex. Synthesis and crystal structure

Masanobu Tsuchimoto, Hirofumi Iwamoto, Masaaki Kojima, Shigeru Ohba

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9 Citations (Scopus)

Abstract

A novel polymeric nitridomanganese(V) complex with a Schiff base ligand [MnN(salpn)] (H2(salpn): N,N′-disalicylidene-1,3-propanediamine) (1) was prepared by photolysis of the azidomanganese(III) complex, [MnN3salpn)] in acetonitrile. The monomeric complex (2) was obtained by recrystallization of 1 from methanol. X-ray crystal structure analyses of 1 and 2 were carried out. The brown complex 1 has a linear ⋯Mn≡N⋯Mn≡N⋯ chain structure.

Original languageEnglish
Pages (from-to)1156-1157
Number of pages2
JournalChemistry Letters
Issue number10
Publication statusPublished - 2000

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Schiff Bases
Photolysis
Methanol
Crystal structure
Ligands
X rays
trimethylenediamine
oligomycin sensitivity-conferring protein
acetonitrile

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Polymeric and monomeric forms of a schiff base-nitridomanganese(V) complex. Synthesis and crystal structure. / Tsuchimoto, Masanobu; Iwamoto, Hirofumi; Kojima, Masaaki; Ohba, Shigeru.

In: Chemistry Letters, No. 10, 2000, p. 1156-1157.

Research output: Contribution to journalArticle

Tsuchimoto, Masanobu ; Iwamoto, Hirofumi ; Kojima, Masaaki ; Ohba, Shigeru. / Polymeric and monomeric forms of a schiff base-nitridomanganese(V) complex. Synthesis and crystal structure. In: Chemistry Letters. 2000 ; No. 10. pp. 1156-1157.
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