Abstract
Recently, various techniques have been developed using photonic crystals. Liquid crystals (LC) confined in a nanodroplet mimicked photonic crystals, such as those of opal. Therefore, investigating the phase behaviour of LC molecules in nanodroplets is very important in the next-generation optical field. In this study, the chemical interaction between surfactants and LCs in nanodroplets is reproduced using a dissipative particle dynamics method. We identify the phase behaviour of LCs and investigate how the chemical interaction affect on the orientation of LCs. In particular, by adding surfactant molecules, various morphological behaviours were observed in the LC nanodroplet. The phase transition temperature varied depending on RND (amount of surfactant molecules). Furthermore, difference of the self-assembly structure also appeared inside the droplet depending on RND. Our simulation offers a theoretical guide to control morphologies of self-assembled LCs inside a nanodroplet, a novel system that may find applications in nanofluidic devices or in photonic crystal technology.
| Original language | English |
|---|---|
| Journal | Liquid Crystals |
| DOIs | |
| Publication status | Published - 2019 Jan 1 |
| Externally published | Yes |
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Keywords
- confined system
- dissipative particle dynamics method
- Liquid crystal
- photonic crystal
- surfactant
ASJC Scopus subject areas
- Chemistry(all)
- Materials Science(all)
- Condensed Matter Physics
Cite this
Polymorphic transitions mediated by surfactants in liquid crystal nanodroplet. / Tsujinoue, Hiroaki; Inokuchi, Takuya; Arai, Noriyoshi.
In: Liquid Crystals, 01.01.2019.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Polymorphic transitions mediated by surfactants in liquid crystal nanodroplet
AU - Tsujinoue, Hiroaki
AU - Inokuchi, Takuya
AU - Arai, Noriyoshi
PY - 2019/1/1
Y1 - 2019/1/1
N2 - Recently, various techniques have been developed using photonic crystals. Liquid crystals (LC) confined in a nanodroplet mimicked photonic crystals, such as those of opal. Therefore, investigating the phase behaviour of LC molecules in nanodroplets is very important in the next-generation optical field. In this study, the chemical interaction between surfactants and LCs in nanodroplets is reproduced using a dissipative particle dynamics method. We identify the phase behaviour of LCs and investigate how the chemical interaction affect on the orientation of LCs. In particular, by adding surfactant molecules, various morphological behaviours were observed in the LC nanodroplet. The phase transition temperature varied depending on RND (amount of surfactant molecules). Furthermore, difference of the self-assembly structure also appeared inside the droplet depending on RND. Our simulation offers a theoretical guide to control morphologies of self-assembled LCs inside a nanodroplet, a novel system that may find applications in nanofluidic devices or in photonic crystal technology.
AB - Recently, various techniques have been developed using photonic crystals. Liquid crystals (LC) confined in a nanodroplet mimicked photonic crystals, such as those of opal. Therefore, investigating the phase behaviour of LC molecules in nanodroplets is very important in the next-generation optical field. In this study, the chemical interaction between surfactants and LCs in nanodroplets is reproduced using a dissipative particle dynamics method. We identify the phase behaviour of LCs and investigate how the chemical interaction affect on the orientation of LCs. In particular, by adding surfactant molecules, various morphological behaviours were observed in the LC nanodroplet. The phase transition temperature varied depending on RND (amount of surfactant molecules). Furthermore, difference of the self-assembly structure also appeared inside the droplet depending on RND. Our simulation offers a theoretical guide to control morphologies of self-assembled LCs inside a nanodroplet, a novel system that may find applications in nanofluidic devices or in photonic crystal technology.
KW - confined system
KW - dissipative particle dynamics method
KW - Liquid crystal
KW - photonic crystal
KW - surfactant
UR - http://www.scopus.com/inward/record.url?scp=85061012475&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=85061012475&partnerID=8YFLogxK
U2 - 10.1080/02678292.2019.1573326
DO - 10.1080/02678292.2019.1573326
M3 - Article
AN - SCOPUS:85061012475
JO - Liquid Crystals
JF - Liquid Crystals
SN - 0267-8292
ER -