Practical Glycosidation Method of Glycals Using Montmorillonite K-10 as an Environmentally Acceptable and Inexpensive Industrial Catalyst

Kazunobu Toshima, Toru Ishizuka, Goh Matsuo, Masaya Nakata

Research output: Contribution to journalArticle

71 Citations (Scopus)

Abstract

The O-glycosidations of glycals, 3,4-di-O-acetyl-L-rhamnal (1) and 3,4,6-tri-O-acetyl-D-glucal (2), with several alcohols using an acidic clay, montmorillonite K-10, as an environmentally acceptable and inexpensive industrial catalyst under mild conditions proceeded effectively to give the corresponding 2,3-unsaturated O-glycosides in high yields.

Original languageEnglish
Pages (from-to)306-308
Number of pages3
JournalSynlett
Volume1995
Issue number4
DOIs
Publication statusPublished - 1995 Apr

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Keywords

  • 2,3-unsaturated O -glycoside
  • glycal
  • glycosidation
  • industrial catalyst
  • montmorillonite K-10

ASJC Scopus subject areas

  • Organic Chemistry

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