Practical Glycosidation Method of Glycals Using Montmorillonite K-10 as an Environmentally Acceptable and Inexpensive Industrial Catalyst

Kazunobu Toshima; Toru Ishizuka; Goh Matsuo; Masaya Nakata

doi:10.1002/chin.199538258

Practical Glycosidation Method of Glycals Using Montmorillonite K-10 as an Environmentally Acceptable and Inexpensive Industrial Catalyst

Kazunobu Toshima, Toru Ishizuka, Goh Matsuo, Masaya Nakata

Department of Applied Chemistry

Research output: Contribution to journal › Article › peer-review

78 Citations (Scopus)

Abstract

The O-glycosidations of glycals, 3,4-di-O-acetyl-L-rhamnal (1) and 3,4,6-tri-O-acetyl-D-glucal (2), with several alcohols using an acidic clay, montmorillonite K-10, as an environmentally acceptable and inexpensive industrial catalyst under mild conditions proceeded effectively to give the corresponding 2,3-unsaturated O-glycosides in high yields.

Original language	English
Pages (from-to)	306-308
Number of pages	3
Journal	Synlett
Volume	1995
Issue number	4
DOIs	https://doi.org/10.1002/chin.199538258
Publication status	Published - 1995 Apr

Keywords

2,3-unsaturated O -glycoside
glycal
glycosidation
industrial catalyst
montmorillonite K-10

ASJC Scopus subject areas

Organic Chemistry

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10.1002/chin.199538258

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abstract = "The O-glycosidations of glycals, 3,4-di-O-acetyl-L-rhamnal (1) and 3,4,6-tri-O-acetyl-D-glucal (2), with several alcohols using an acidic clay, montmorillonite K-10, as an environmentally acceptable and inexpensive industrial catalyst under mild conditions proceeded effectively to give the corresponding 2,3-unsaturated O-glycosides in high yields.",

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AU - Matsuo, Goh

AU - Nakata, Masaya

PY - 1995/4

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AB - The O-glycosidations of glycals, 3,4-di-O-acetyl-L-rhamnal (1) and 3,4,6-tri-O-acetyl-D-glucal (2), with several alcohols using an acidic clay, montmorillonite K-10, as an environmentally acceptable and inexpensive industrial catalyst under mild conditions proceeded effectively to give the corresponding 2,3-unsaturated O-glycosides in high yields.

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KW - glycal

KW - glycosidation

KW - industrial catalyst

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Practical Glycosidation Method of Glycals Using Montmorillonite K-10 as an Environmentally Acceptable and Inexpensive Industrial Catalyst

Abstract

Keywords

ASJC Scopus subject areas

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