Preparation and characterization of mono-imidazole ligated (meso-tetramesitylporphyrinato)iron(III) complexes

Model for cytochromes c'

Akira Ikezaki, Mikio Nakamura

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

A series of mono-imidazole ligated (meso-tetramesitylporphyrinato)iron(III) complexes have been prepared. The spin states of these complexes are presented as the admixed intermediate (S = 3/2, 5/2) on the basis of the 1H NMR, 13C NMR, EPR, and magnetic moments. The S = 3/2 character has increased as the axial imidazole ligand becomes bulkier.

Original languageEnglish
Pages (from-to)994-995
Number of pages2
JournalChemistry Letters
Issue number9
Publication statusPublished - 2000

Fingerprint

Cytochromes c'
Iron
Nuclear magnetic resonance
Magnetic moments
Paramagnetic resonance
Ligands
imidazole

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Preparation and characterization of mono-imidazole ligated (meso-tetramesitylporphyrinato)iron(III) complexes : Model for cytochromes c'. / Ikezaki, Akira; Nakamura, Mikio.

In: Chemistry Letters, No. 9, 2000, p. 994-995.

Research output: Contribution to journalArticle

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