Preparation and characterization of mono-imidazole ligated (meso-tetramesitylporphyrinato)iron(III) complexes: Model for cytochromes c'

Akira Ikezaki, Mikio Nakamura

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Abstract

A series of mono-imidazole ligated (meso-tetramesitylporphyrinato)iron(III) complexes have been prepared. The spin states of these complexes are presented as the admixed intermediate (S = 3/2, 5/2) on the basis of the 1H NMR, 13C NMR, EPR, and magnetic moments. The S = 3/2 character has increased as the axial imidazole ligand becomes bulkier.

Original languageEnglish
Pages (from-to)994-995
Number of pages2
JournalChemistry Letters
Issue number9
DOIs
Publication statusPublished - 2000 Jan 1

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ASJC Scopus subject areas

  • Chemistry(all)

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