Preparation and lithium insertion behaviour of SrII substituted δ-SryAg0.75-2yV2O5

Jin Kawakita; Rika Shimizu; Yasushi Katayama; Takashi Miura; Tomiya Kishi

doi:10.1016/S0167-2738(99)00056-9

Preparation and lithium insertion behaviour of Sr^II substituted δ-Sr_yAg_0.75-2yV₂O₅

Jin Kawakita, Rika Shimizu, Yasushi Katayama, Takashi Miura, Tomiya Kishi

Department of Applied Chemistry

Research output: Contribution to journal › Article

5 Citations (Scopus)

Abstract

Preparation of Sr^II substituted δ-Sr_yAg_0.75-2yV₂O₅ and its lithium insertion behaviour were investigated. Isostructural substitution is possible within y = 0.1. Lithium insertion proceeded in three steps, and in the first step lithium insertion occurs in the single phase, the limiting composition of which is controlled by the ratio of V^IV to V^V in the oxide. Reversibility in insertion/extraction cycle is improve by Sr^II substitution.

Original language	English
Pages (from-to)	181-188
Number of pages	8
Journal	Solid State Ionics
Volume	123
Issue number	1
DOIs	https://doi.org/10.1016/S0167-2738(99)00056-9
Publication status	Published - 1999 Aug

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ASJC Scopus subject areas

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

Cite this

Kawakita, J., Shimizu, R., Katayama, Y., Miura, T., & Kishi, T. (1999). Preparation and lithium insertion behaviour of Sr^II substituted δ-Sr_yAg_0.75-2yV₂O₅. Solid State Ionics, 123(1), 181-188. https://doi.org/10.1016/S0167-2738(99)00056-9

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AB - Preparation of SrII substituted δ-SryAg0.75-2yV2O5 and its lithium insertion behaviour were investigated. Isostructural substitution is possible within y = 0.1. Lithium insertion proceeded in three steps, and in the first step lithium insertion occurs in the single phase, the limiting composition of which is controlled by the ratio of VIV to VV in the oxide. Reversibility in insertion/extraction cycle is improve by SrII substitution.

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10.1016/S0167-2738(99)00056-9