Preparation and molecular structures of [Co,(S2O- S,S')(Me2PCH2CH2PMe2)2]ClO4 and [Co(S2PMe2)2(Me2PCH2CH2PMe2)]BF4

M. Kita; K. Kashiwabara; J. Fujita; S. Kurachi; S. Ohba

doi:10.1246/bcsj.66.3686

Preparation and molecular structures of [Co,(S₂O- S,S')(Me₂PCH₂CH₂PMe₂)₂]ClO₄ and [Co(S₂PMe₂)₂(Me₂PCH₂CH₂PMe₂)]BF₄

M. Kita, K. Kashiwabara, J. Fujita, S. Kurachi, S. Ohba

Department of Humanities and Social Sciences

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

The reaction of elemental sulfur S₈ with [Co(dmpe)₂](BF₄)₂ in a mixture of methanol and benzene gave a novel S,S'-coordinated disulfur oxide cobalt(III) complex, [Co(S₂O-S,S')(dmpe)₂]ClO₄ (1), and a dimethyldithiophosphinato complex. [Co(S₂PMe₂)₂(dmpe)]BF₄ (2). The molecular structures of these complexes were determined by X-ray structure analyses. Crystal data for complex 1: monoclinic, P2₁/n, a=14.702(3), b=11.645(1), c=14.333(2) Å, β=109.90(2)°, V=2307.4(2) Å³. D(x)=1.55, D(m)=1.54(3) g cm^-3. Z=4, R=0.039 for 4542 reflections. Crystal data for complex 2: orthorhombic, Pnc2, a=13.383(3), b=12.333(2), c=13.742(3) Å, V=2268.1(8) Å³, D(x)=1.60, D(m)=1.59(2) g cm^-3, Z=4, R=0.075 for 2060 reflections. The central sulfur atom of the S-S-O group in complex 1 exerts a larger trans influence than does the terminal sulfur.

Original language	English
Pages (from-to)	3686-3692
Number of pages	7
Journal	Bulletin of the Chemical Society of Japan
Volume	66
Issue number	12
DOIs	https://doi.org/10.1246/bcsj.66.3686
Publication status	Published - 1993 Jan 1

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Chemistry(all)

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@article{27eff9e92e5d454a9ac7b89c8249b7f3,

title = "Preparation and molecular structures of [Co,(S2O- S,S')(Me2PCH2CH2PMe2)2]ClO4 and [Co(S2PMe2)2(Me2PCH2CH2PMe2)]BF4",

abstract = "The reaction of elemental sulfur S8 with [Co(dmpe)2](BF4)2 in a mixture of methanol and benzene gave a novel S,S'-coordinated disulfur oxide cobalt(III) complex, [Co(S2O-S,S')(dmpe)2]ClO4 (1), and a dimethyldithiophosphinato complex. [Co(S2PMe2)2(dmpe)]BF4 (2). The molecular structures of these complexes were determined by X-ray structure analyses. Crystal data for complex 1: monoclinic, P21/n, a=14.702(3), b=11.645(1), c=14.333(2) {\AA}, β=109.90(2)°, V=2307.4(2) {\AA}3. D(x)=1.55, D(m)=1.54(3) g cm-3. Z=4, R=0.039 for 4542 reflections. Crystal data for complex 2: orthorhombic, Pnc2, a=13.383(3), b=12.333(2), c=13.742(3) {\AA}, V=2268.1(8) {\AA}3, D(x)=1.60, D(m)=1.59(2) g cm-3, Z=4, R=0.075 for 2060 reflections. The central sulfur atom of the S-S-O group in complex 1 exerts a larger trans influence than does the terminal sulfur.",

author = "M. Kita and K. Kashiwabara and J. Fujita and S. Kurachi and S. Ohba",

year = "1993",

month = jan,

day = "1",

doi = "10.1246/bcsj.66.3686",

language = "English",

volume = "66",

pages = "3686--3692",

journal = "Bulletin of the Chemical Society of Japan",

issn = "0009-2673",

publisher = "Chemical Society of Japan",

number = "12",

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TY - JOUR

T1 - Preparation and molecular structures of [Co,(S2O- S,S')(Me2PCH2CH2PMe2)2]ClO4 and [Co(S2PMe2)2(Me2PCH2CH2PMe2)]BF4

AU - Kita, M.

AU - Kashiwabara, K.

AU - Fujita, J.

AU - Kurachi, S.

AU - Ohba, S.

PY - 1993/1/1

Y1 - 1993/1/1

N2 - The reaction of elemental sulfur S8 with [Co(dmpe)2](BF4)2 in a mixture of methanol and benzene gave a novel S,S'-coordinated disulfur oxide cobalt(III) complex, [Co(S2O-S,S')(dmpe)2]ClO4 (1), and a dimethyldithiophosphinato complex. [Co(S2PMe2)2(dmpe)]BF4 (2). The molecular structures of these complexes were determined by X-ray structure analyses. Crystal data for complex 1: monoclinic, P21/n, a=14.702(3), b=11.645(1), c=14.333(2) Å, β=109.90(2)°, V=2307.4(2) Å3. D(x)=1.55, D(m)=1.54(3) g cm-3. Z=4, R=0.039 for 4542 reflections. Crystal data for complex 2: orthorhombic, Pnc2, a=13.383(3), b=12.333(2), c=13.742(3) Å, V=2268.1(8) Å3, D(x)=1.60, D(m)=1.59(2) g cm-3, Z=4, R=0.075 for 2060 reflections. The central sulfur atom of the S-S-O group in complex 1 exerts a larger trans influence than does the terminal sulfur.

AB - The reaction of elemental sulfur S8 with [Co(dmpe)2](BF4)2 in a mixture of methanol and benzene gave a novel S,S'-coordinated disulfur oxide cobalt(III) complex, [Co(S2O-S,S')(dmpe)2]ClO4 (1), and a dimethyldithiophosphinato complex. [Co(S2PMe2)2(dmpe)]BF4 (2). The molecular structures of these complexes were determined by X-ray structure analyses. Crystal data for complex 1: monoclinic, P21/n, a=14.702(3), b=11.645(1), c=14.333(2) Å, β=109.90(2)°, V=2307.4(2) Å3. D(x)=1.55, D(m)=1.54(3) g cm-3. Z=4, R=0.039 for 4542 reflections. Crystal data for complex 2: orthorhombic, Pnc2, a=13.383(3), b=12.333(2), c=13.742(3) Å, V=2268.1(8) Å3, D(x)=1.60, D(m)=1.59(2) g cm-3, Z=4, R=0.075 for 2060 reflections. The central sulfur atom of the S-S-O group in complex 1 exerts a larger trans influence than does the terminal sulfur.

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U2 - 10.1246/bcsj.66.3686

DO - 10.1246/bcsj.66.3686

M3 - Article

AN - SCOPUS:0027859048

SN - 0009-2673

VL - 66

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EP - 3692

JO - Bulletin of the Chemical Society of Japan

JF - Bulletin of the Chemical Society of Japan

IS - 12

ER -

Preparation and molecular structures of [Co,(S₂O- S,S')(Me₂PCH₂CH₂PMe₂)₂]ClO₄ and [Co(S₂PMe₂)₂(Me₂PCH₂CH₂PMe₂)]BF₄

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