Preparation and photoluminescence properties of yellow-emitting CuInS2/ZnS quantum dots embedded in TMAS-derived silica

Chikako Wada, Yoshiki Iso, Tetsuhiko Isobe, Hirokazu Sasaki

Research output: Contribution to journalArticlepeer-review

20 Citations (Scopus)


The degradation of CuInS2 (CIS) quantum dots (QDs) under excitation light due to photo-oxidization by O2 has been a significant problem. Embedding QDs into a matrix to protect them against O2 would improve their photostability. In this paper, hydrophilized CIS/ZnS/ZnS QDs prepared by a ligand exchange method were embedded in silica through a sol-gel method using tetramethylammonium silicate (TMAS) aqueous solution, in which negatively-charged nanoparticles can be well dispersed. QDs modified with 3-mercaptopropionic acid (MPA) were well dispersed into TMAS-derived silica. The obtained monolithic TMAS-derived silica composites containing embedded MPA-modified CIS/ZnS/ZnS QDs exhibited high photoluminescence (PL) quantum yields (43-47%). Changes in PL intensity under continuous excitation were measured to evaluate the photostability of the QDs. The PL intensity of the composite was 105% that of the initial value after 5 h irradiation, while the PL intensities of as-prepared QDs and a PMMA composite decreased to 88% and 92%, respectively. The good gas barrier properties of TMAS-derived silica likely caused the high photostability by preventing O2 from reaching the surface of the embedded QDs.

Original languageEnglish
Pages (from-to)7936-7943
Number of pages8
JournalRSC Advances
Issue number13
Publication statusPublished - 2017

ASJC Scopus subject areas

  • Chemistry(all)
  • Chemical Engineering(all)


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