Preparation of 94 K-superconducting NdBa2Cu3O7-δ without post-anneal in oxygen

Shinobu Fujihara, N. Yoshida, T. Kimura

Research output: Contribution to journalArticle

14 Citations (Scopus)

Abstract

The preparation of the polycrystalline NdBa2Cu3O7-δ superconductor using Ba2Cu3O5+x as a precursor has been studied. Ba2Cu3O5+x was prepared by the sol-gel process using metal acetates as starting materials, tartaric acid as an chelating reagent and water as solvent. The gel was heated at 780°C for 60 h in O2 to form the Ba2Cu3O5+x. precursor. The value of x in Ba2Cu3O5+x was determined to be 0.5; that is, copper was in a highly oxidized state over +2. NdBa2Cu3O7-δ was obtained by the solid-state reaction between Nd2O3 and Ba2Cu3O5+x heated at 900°C for 20 h in N2. Although the sample did not undergo post-anneal in oxygen, it showed good superconducting properties; Tc of 94 K and the intragranular Jc of 3.7 × 105 A/cm2 under a field of 50 kOe at 20 K. The advantage of using Ba2Cu3O5+x is considered to be its sufficient amount of oxygen as well as prevention of the Nd3+/Ba2+ substitution.

Original languageEnglish
Pages (from-to)69-74
Number of pages6
JournalPhysica C: Superconductivity and its Applications
Volume276
Issue number1-2
Publication statusPublished - 1997 Mar 1

Fingerprint

Oxygen
preparation
oxygen
sol-gel processes
Chelation
Solid state reactions
Sol-gel process
Superconducting materials
reagents
Copper
acetates
Acetates
Substitution reactions
Gels
Metals
gels
substitutes
solid state
copper
acids

Keywords

  • BaCuO
  • Critical current density
  • Magnetization
  • NdBaCuO
  • Sol-gel

ASJC Scopus subject areas

  • Condensed Matter Physics

Cite this

Preparation of 94 K-superconducting NdBa2Cu3O7-δ without post-anneal in oxygen. / Fujihara, Shinobu; Yoshida, N.; Kimura, T.

In: Physica C: Superconductivity and its Applications, Vol. 276, No. 1-2, 01.03.1997, p. 69-74.

Research output: Contribution to journalArticle

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