Preparation of gold nanoparticles using well-defined thermosensitive polymers: Catalytic activity and reusability for aerobic alcohol oxidation in water

Yukiko Fukuyama, Naoto Yagi, Shokyoku Kanaoka, Sadahito Aoshima, Hironori Tsunoyama, Tatsuya Tsukuda, Hidehiro Sakurai

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

Gold nanoparticles of ca. 3 nm with a narrow size distribution were prepared using block or star-shaped polymers of vinyl ethers with pendant oxyethlene chains as a template in water. The polymers were synthesized by living cationic polymerization in the presence of an added base. Auric ions, weakly interacted with the oxyethylene units, were reduced with sodium borohydride to yield polymer-stabilized gold nanoparticles. These particles were shown to catalyze aerobic oxidation of benzylic alcohol in water at room temperature. Moreover, the reuse of the catalysts was examined by utilizing thermosensitivity of the polymer chains.

Original languageEnglish
Title of host publicationPolymer Preprints, Japan
Pages2641-2642
Number of pages2
Volume55
Edition2
Publication statusPublished - 2006
Externally publishedYes
Event55th Society of Polymer Science Japan Symposium on Macromolecules - Toyama, Japan
Duration: 2006 Sep 202006 Sep 22

Other

Other55th Society of Polymer Science Japan Symposium on Macromolecules
CountryJapan
CityToyama
Period06/9/2006/9/22

Fingerprint

Reusability
Catalyst activity
Alcohols
Gold
Nanoparticles
Oxidation
Polymers
Water
Cationic polymerization
Living polymerization
Stars
Ethers
Sodium
Catalysts
Ions
Temperature

Keywords

  • Alcohol oxidation
  • Cationic polymerization
  • Gold nanoparticle
  • Living polymerization
  • Metal catalyst
  • Thermosensitive polymer

ASJC Scopus subject areas

  • Engineering(all)

Cite this

Fukuyama, Y., Yagi, N., Kanaoka, S., Aoshima, S., Tsunoyama, H., Tsukuda, T., & Sakurai, H. (2006). Preparation of gold nanoparticles using well-defined thermosensitive polymers: Catalytic activity and reusability for aerobic alcohol oxidation in water. In Polymer Preprints, Japan (2 ed., Vol. 55, pp. 2641-2642)

Preparation of gold nanoparticles using well-defined thermosensitive polymers : Catalytic activity and reusability for aerobic alcohol oxidation in water. / Fukuyama, Yukiko; Yagi, Naoto; Kanaoka, Shokyoku; Aoshima, Sadahito; Tsunoyama, Hironori; Tsukuda, Tatsuya; Sakurai, Hidehiro.

Polymer Preprints, Japan. Vol. 55 2. ed. 2006. p. 2641-2642.

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Fukuyama, Y, Yagi, N, Kanaoka, S, Aoshima, S, Tsunoyama, H, Tsukuda, T & Sakurai, H 2006, Preparation of gold nanoparticles using well-defined thermosensitive polymers: Catalytic activity and reusability for aerobic alcohol oxidation in water. in Polymer Preprints, Japan. 2 edn, vol. 55, pp. 2641-2642, 55th Society of Polymer Science Japan Symposium on Macromolecules, Toyama, Japan, 06/9/20.
Fukuyama Y, Yagi N, Kanaoka S, Aoshima S, Tsunoyama H, Tsukuda T et al. Preparation of gold nanoparticles using well-defined thermosensitive polymers: Catalytic activity and reusability for aerobic alcohol oxidation in water. In Polymer Preprints, Japan. 2 ed. Vol. 55. 2006. p. 2641-2642
Fukuyama, Yukiko ; Yagi, Naoto ; Kanaoka, Shokyoku ; Aoshima, Sadahito ; Tsunoyama, Hironori ; Tsukuda, Tatsuya ; Sakurai, Hidehiro. / Preparation of gold nanoparticles using well-defined thermosensitive polymers : Catalytic activity and reusability for aerobic alcohol oxidation in water. Polymer Preprints, Japan. Vol. 55 2. ed. 2006. pp. 2641-2642
@inproceedings{9a95fdb9eca3402d82325b304c44d84f,
title = "Preparation of gold nanoparticles using well-defined thermosensitive polymers: Catalytic activity and reusability for aerobic alcohol oxidation in water",
abstract = "Gold nanoparticles of ca. 3 nm with a narrow size distribution were prepared using block or star-shaped polymers of vinyl ethers with pendant oxyethlene chains as a template in water. The polymers were synthesized by living cationic polymerization in the presence of an added base. Auric ions, weakly interacted with the oxyethylene units, were reduced with sodium borohydride to yield polymer-stabilized gold nanoparticles. These particles were shown to catalyze aerobic oxidation of benzylic alcohol in water at room temperature. Moreover, the reuse of the catalysts was examined by utilizing thermosensitivity of the polymer chains.",
keywords = "Alcohol oxidation, Cationic polymerization, Gold nanoparticle, Living polymerization, Metal catalyst, Thermosensitive polymer",
author = "Yukiko Fukuyama and Naoto Yagi and Shokyoku Kanaoka and Sadahito Aoshima and Hironori Tsunoyama and Tatsuya Tsukuda and Hidehiro Sakurai",
year = "2006",
language = "English",
volume = "55",
pages = "2641--2642",
booktitle = "Polymer Preprints, Japan",
edition = "2",

}

TY - GEN

T1 - Preparation of gold nanoparticles using well-defined thermosensitive polymers

T2 - Catalytic activity and reusability for aerobic alcohol oxidation in water

AU - Fukuyama, Yukiko

AU - Yagi, Naoto

AU - Kanaoka, Shokyoku

AU - Aoshima, Sadahito

AU - Tsunoyama, Hironori

AU - Tsukuda, Tatsuya

AU - Sakurai, Hidehiro

PY - 2006

Y1 - 2006

N2 - Gold nanoparticles of ca. 3 nm with a narrow size distribution were prepared using block or star-shaped polymers of vinyl ethers with pendant oxyethlene chains as a template in water. The polymers were synthesized by living cationic polymerization in the presence of an added base. Auric ions, weakly interacted with the oxyethylene units, were reduced with sodium borohydride to yield polymer-stabilized gold nanoparticles. These particles were shown to catalyze aerobic oxidation of benzylic alcohol in water at room temperature. Moreover, the reuse of the catalysts was examined by utilizing thermosensitivity of the polymer chains.

AB - Gold nanoparticles of ca. 3 nm with a narrow size distribution were prepared using block or star-shaped polymers of vinyl ethers with pendant oxyethlene chains as a template in water. The polymers were synthesized by living cationic polymerization in the presence of an added base. Auric ions, weakly interacted with the oxyethylene units, were reduced with sodium borohydride to yield polymer-stabilized gold nanoparticles. These particles were shown to catalyze aerobic oxidation of benzylic alcohol in water at room temperature. Moreover, the reuse of the catalysts was examined by utilizing thermosensitivity of the polymer chains.

KW - Alcohol oxidation

KW - Cationic polymerization

KW - Gold nanoparticle

KW - Living polymerization

KW - Metal catalyst

KW - Thermosensitive polymer

UR - http://www.scopus.com/inward/record.url?scp=33846139317&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=33846139317&partnerID=8YFLogxK

M3 - Conference contribution

AN - SCOPUS:33846139317

VL - 55

SP - 2641

EP - 2642

BT - Polymer Preprints, Japan

ER -