Preparation of Sodium Ion-Sensing Plates Based on a Thin Layer Liquid Membrane Containing a Neutral Ionophore and a Lipophilic Anionic Dye

Hideaki Hisamoto; Sayaka Sato; Kazunari Sato; Dwi Siswanta; Koji Suzuki

doi:10.2116/analsci.14.127

Preparation of Sodium Ion-Sensing Plates Based on a Thin Layer Liquid Membrane Containing a Neutral Ionophore and a Lipophilic Anionic Dye

Hideaki Hisamoto, Sayaka Sato, Kazunari Sato, Dwi Siswanta, Koji Suzuki

Department of Applied Chemistry

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

A sodium ion-sensing plate was prepared as an easily-handled ion-sensing optical chemical sensor (optode) probe. The sensing plate consisted of an ion-sensing liquid thin layer containing a Na ⁺ -selective neutral ionophore (16-crown-5 derivatives) and a lipophilic anionic dye (KD-A3), which was placed on a chemically modified (octadecyl silanized) frosted glass plate that was covered with a cellulose dialysis membrane. This ion-sensing plate can easily determine Na ⁺ ranging from 10 ^-4 to10 ^-1 M by simply dipping the plate into the sample solution. The response time was ca. 80 s for 10 ^-1 M NaCl with good reproducibility (relative standard deviation (RSD)=±1.33% for ten sequential measurements).

Original language	English
Pages (from-to)	127-131
Number of pages	5
Journal	analytical sciences
Volume	14
Issue number	1
DOIs	https://doi.org/10.2116/analsci.14.127
Publication status	Published - 1998

Keywords

Ion-selective optode
Lipophilic anionic dye
Neutral ionophore
Optical sensor
Sensing plate

ASJC Scopus subject areas

Analytical Chemistry

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title = "Preparation of Sodium Ion-Sensing Plates Based on a Thin Layer Liquid Membrane Containing a Neutral Ionophore and a Lipophilic Anionic Dye",

abstract = " A sodium ion-sensing plate was prepared as an easily-handled ion-sensing optical chemical sensor (optode) probe. The sensing plate consisted of an ion-sensing liquid thin layer containing a Na + -selective neutral ionophore (16-crown-5 derivatives) and a lipophilic anionic dye (KD-A3), which was placed on a chemically modified (octadecyl silanized) frosted glass plate that was covered with a cellulose dialysis membrane. This ion-sensing plate can easily determine Na + ranging from 10 -4 to10 -1 M by simply dipping the plate into the sample solution. The response time was ca. 80 s for 10 -1 M NaCl with good reproducibility (relative standard deviation (RSD)=±1.33% for ten sequential measurements). ",

keywords = "Ion-selective optode, Lipophilic anionic dye, Neutral ionophore, Optical sensor, Sensing plate",

author = "Hideaki Hisamoto and Sayaka Sato and Kazunari Sato and Dwi Siswanta and Koji Suzuki",

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AU - Sato, Sayaka

AU - Sato, Kazunari

AU - Siswanta, Dwi

AU - Suzuki, Koji

PY - 1998

Y1 - 1998

N2 - A sodium ion-sensing plate was prepared as an easily-handled ion-sensing optical chemical sensor (optode) probe. The sensing plate consisted of an ion-sensing liquid thin layer containing a Na + -selective neutral ionophore (16-crown-5 derivatives) and a lipophilic anionic dye (KD-A3), which was placed on a chemically modified (octadecyl silanized) frosted glass plate that was covered with a cellulose dialysis membrane. This ion-sensing plate can easily determine Na + ranging from 10 -4 to10 -1 M by simply dipping the plate into the sample solution. The response time was ca. 80 s for 10 -1 M NaCl with good reproducibility (relative standard deviation (RSD)=±1.33% for ten sequential measurements).

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KW - Lipophilic anionic dye

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KW - Optical sensor

KW - Sensing plate

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Preparation of Sodium Ion-Sensing Plates Based on a Thin Layer Liquid Membrane Containing a Neutral Ionophore and a Lipophilic Anionic Dye

Abstract

Keywords

ASJC Scopus subject areas

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