Pressure effects and Mössbauer spectroscopic studies on a 3D mixed-valence iron spin-crossover complex with NiAs topology

Yue Ling Bai, Jun Tao, Rong Bin Huang, Lan Sun Zheng, Shao Liang Zheng, Kazuyoshi Oshida, Yasuaki Einaga

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57 Citations (Scopus)


A three-dimensional mixed-valence iron complex with NiAs-type topology, [(FeIII3O)FeII(TA)6(H 2O)3]•(ClO4)2(NO 3)(EtOH)(H2O)2 (1, HTA = tetrazole-1H-acetic acid), shows spin-crossover behavior that was characterized via variable-temperature crystal structures, Mössbauer spectra and magnetic susceptibilities, the pressure effects on the transition behavior were also studied.

Original languageEnglish
Pages (from-to)1753-1755
Number of pages3
JournalChemical Communications
Issue number15
Publication statusPublished - 2008 Apr 9


ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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