Abstract
A three-dimensional mixed-valence iron complex with NiAs-type topology, [(FeIII3O)FeII(TA)6(H 2O)3]•(ClO4)2(NO 3)(EtOH)(H2O)2 (1, HTA = tetrazole-1H-acetic acid), shows spin-crossover behavior that was characterized via variable-temperature crystal structures, Mössbauer spectra and magnetic susceptibilities, the pressure effects on the transition behavior were also studied.
Original language | English |
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Pages (from-to) | 1753-1755 |
Number of pages | 3 |
Journal | Chemical Communications |
Issue number | 15 |
DOIs | |
Publication status | Published - 2008 |
ASJC Scopus subject areas
- Catalysis
- Electronic, Optical and Magnetic Materials
- Ceramics and Composites
- Chemistry(all)
- Surfaces, Coatings and Films
- Metals and Alloys
- Materials Chemistry