Pyramidal structures of lanthanide-C60 clusters (Lnn(C60)m: Ln = Eu and Ho)

Atsushi Nakajima, S. Nagao, Y. Negishi, A. Kato, Y. Nakamura

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Abstract

A two-laser vaporization method produced novel lanthanide organometallic culsters, Lnn(C60)m, consisting of lanthanide atoms (Ln; Ln = Eu and Ho) and C60 molecules in the gas phase. The Lnn(C60)m clusters were produced predominantly at compositions of (n,m) = (n, n + 3) [n = 1-4]. These stoichiometries revealed no chemisorption reactivity toward CCl4 and O2 reactants. The cluster having (1,4) composition was proposed to form a tetrahedral structure, in which a Ln atom was surrounded by four C60 molecules. In larger clusters with (n, n + 3) composition, each Ln atom was in a local (1,4) group. Ln1(C60)m clusters were charge-transfer complexes expressed as Ln1x+(C60)mx+, and that Eu and Ho atoms existed as Eu2+ and Ho3+ ions, respectively.

Original languageEnglish
Pages (from-to)8909-8914
Number of pages6
JournalJournal of Physical Chemistry A
Volume103
Issue number45
DOIs
Publication statusPublished - 1999 Nov 11

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ASJC Scopus subject areas

  • Physical and Theoretical Chemistry

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