Quantitative Sequential Photoenergy Conversion Process from Singlet Fission to Intermolecular Two-Electron Transfers Utilizing Tetracene Dimer

Shunta Nakamura, Hayato Sakai, Hiroki Nagashima, Yasuhiro Kobori, Nikolai V. Tkachenko, Taku Hasobe

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

Singlet fission (SF) theoretically enables the performance of the sequential photoenergy conversion process starting from the singlet state and leading to electron transfer (ET) with the radical ion pair quantum yield approaching 200%. Additionally, the long lifetime of the triplet state opens the possibility for an intermolecular ET process in a diffusion-limited reaction. However, the quantitative two-electron transfer process through SF has yet to be reported. Herein we demonstrate the quantitative sequential process involving SF and leading to intermolecular two-electron transfers using 2,2′-biphenyl-bridged tetracene dimer (Tet-BP-Tet: SF and electron donor) and chloranil (Ch: electron acceptor). The high-yield and long-lived individual triplet excited states of Tet-BP-Tet by SF (φT = 175 ± 5% and τT = 0.29 ms) resulted in the quantitative two-electron transfer process (φET = 173 ± 5%) with Ch in benzonitrile.

Original languageEnglish
Pages (from-to)26-31
Number of pages6
JournalACS Energy Letters
Volume4
Issue number1
DOIs
Publication statusPublished - 2019 Jan 11

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ASJC Scopus subject areas

  • Chemistry (miscellaneous)
  • Renewable Energy, Sustainability and the Environment
  • Fuel Technology
  • Energy Engineering and Power Technology
  • Materials Chemistry

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