Quartz crystal microbalance sensor using ionophore for ammonium ion detection

Yasuhiro Kosaki, Kosuke Takano, Daniel Citterio, Koji Suzuki, Seimei Shiratori

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

Ionophore-based quartz crystal microbalance (QCM) ammonium ion sensors with a detection limit for ammonium ion concentrations as low as 2.2.M were fabricated. Ionophores are molecules, which selectively bind a particular ion. In this study, one of the known ionophores for ammonium, nonactin, was used to detect ammonium ions for environmental in-situ monitoring of aquarium water for the first time. To fabricate the sensing films, poly(vinyl chloride) was used as the matrix for the immobilization of nonactin. Furthermore, the anionic additive, tetrakis (4-chlorophenyl) borate potassium salt and the plasticizer dioctyl sebacate were used to enhance the sensor properties. The sensor allowed detecting ammonium ions not only in static solution, but also in flowing water. The sensor showed a nearly linear response with the increase of the ammonium ion concentration. The QCM resonance frequency increased with the increase of ammonium ion concentration, suggesting a decreasing weight of the sensing film. The detailed response mechanism could not be verified yet. However, from the results obtained when using a different plasticizer, nitrophenyl octyl ether, it is considered that this effect is caused by the release of water molecules. Consequently, the newly fabricated sensor detects ammonium ions by discharge of water. It shows high selectivity over potassium and sodium ions. We conclude that the newly fabricated sensor can be applied for detecting ammonium ions in aquarium water, since it allows measuring low ammonium ion concentrations. This sensor will be usable for water quality monitoring and controlling.

Original languageEnglish
Pages (from-to)563-567
Number of pages5
JournalJournal of Nanoscience and Nanotechnology
Volume12
Issue number1
DOIs
Publication statusPublished - 2012

Fingerprint

Quartz Crystal Microbalance Techniques
Ionophores
Quartz crystal microbalances
quartz crystals
Ammonium Compounds
microbalances
Ions
ion concentration
sensors
Sensors
ions
plasticizers
water
Water
potassium
Plasticizers
water quality
Potassium
borates
immobilization

Keywords

  • Ammonium ion
  • Ionophore
  • Liquid phase
  • Nonactin
  • Quartz crystal microbalance
  • Sensor

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Chemistry(all)
  • Materials Science(all)
  • Bioengineering
  • Biomedical Engineering

Cite this

Quartz crystal microbalance sensor using ionophore for ammonium ion detection. / Kosaki, Yasuhiro; Takano, Kosuke; Citterio, Daniel; Suzuki, Koji; Shiratori, Seimei.

In: Journal of Nanoscience and Nanotechnology, Vol. 12, No. 1, 2012, p. 563-567.

Research output: Contribution to journalArticle

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