R-enantioselective galactosylation of secondary alcohols using β-galactosidase

Shuichi Matsumura; Hiroki Yamazaki; Kazunobu Toshima

doi:10.1023/A:1018357924756

R-enantioselective galactosylation of secondary alcohols using β-galactosidase

Shuichi Matsumura, Hiroki Yamazaki, Kazunobu Toshima

Department of Applied Chemistry

Research output: Contribution to journal › Article › peer-review

11 Citations (Scopus)

Abstract

Significant R-enantioselection occurred for β-galactosyl transfer to the secondary alcohols, 2-butanol, 2-octanol, 3-methyl-2-butanol, 1-phenylethanol, 1,2-propanediol, 1-methoxy-2-propanol and 3-hydroxybutanoates, with β-galactosidase from Escherichia coli. The highest R-enantioselection of 98% e.e. was for the β-galactosylation of 1-phenylethanol using β-galactosidase from E. coli.

Original language	English
Pages (from-to)	583-586
Number of pages	4
Journal	Biotechnology Letters
Volume	19
Issue number	6
DOIs	https://doi.org/10.1023/A:1018357924756
Publication status	Published - 1997

ASJC Scopus subject areas

Biotechnology
Bioengineering
Applied Microbiology and Biotechnology

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title = "R-enantioselective galactosylation of secondary alcohols using β-galactosidase",

abstract = "Significant R-enantioselection occurred for β-galactosyl transfer to the secondary alcohols, 2-butanol, 2-octanol, 3-methyl-2-butanol, 1-phenylethanol, 1,2-propanediol, 1-methoxy-2-propanol and 3-hydroxybutanoates, with β-galactosidase from Escherichia coli. The highest R-enantioselection of 98% e.e. was for the β-galactosylation of 1-phenylethanol using β-galactosidase from E. coli.",

author = "Shuichi Matsumura and Hiroki Yamazaki and Kazunobu Toshima",

year = "1997",

doi = "10.1023/A:1018357924756",

language = "English",

volume = "19",

pages = "583--586",

journal = "Biotechnology Letters",

issn = "0141-5492",

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T1 - R-enantioselective galactosylation of secondary alcohols using β-galactosidase

AU - Matsumura, Shuichi

AU - Yamazaki, Hiroki

AU - Toshima, Kazunobu

PY - 1997

Y1 - 1997

N2 - Significant R-enantioselection occurred for β-galactosyl transfer to the secondary alcohols, 2-butanol, 2-octanol, 3-methyl-2-butanol, 1-phenylethanol, 1,2-propanediol, 1-methoxy-2-propanol and 3-hydroxybutanoates, with β-galactosidase from Escherichia coli. The highest R-enantioselection of 98% e.e. was for the β-galactosylation of 1-phenylethanol using β-galactosidase from E. coli.

AB - Significant R-enantioselection occurred for β-galactosyl transfer to the secondary alcohols, 2-butanol, 2-octanol, 3-methyl-2-butanol, 1-phenylethanol, 1,2-propanediol, 1-methoxy-2-propanol and 3-hydroxybutanoates, with β-galactosidase from Escherichia coli. The highest R-enantioselection of 98% e.e. was for the β-galactosylation of 1-phenylethanol using β-galactosidase from E. coli.

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U2 - 10.1023/A:1018357924756

DO - 10.1023/A:1018357924756

M3 - Article

AN - SCOPUS:0030919012

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VL - 19

SP - 583

EP - 586

JO - Biotechnology Letters

JF - Biotechnology Letters

IS - 6

ER -

R-enantioselective galactosylation of secondary alcohols using β-galactosidase

Abstract

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