Redox reaction in 1-ethyl-3-methylimidazolium-iron chlorides molten salt system for battery application

Yasushi Katayama; Isamu Konishiike; Takashi Miura; Tomiya Kishi

doi:10.1016/S0378-7753(02)00077-0

Redox reaction in 1-ethyl-3-methylimidazolium-iron chlorides molten salt system for battery application

Yasushi Katayama, Isamu Konishiike, Takashi Miura, Tomiya Kishi

Department of Applied Chemistry

Research output: Contribution to journal › Article › peer-review

43 Citations (Scopus)

Abstract

The redox reaction between divalent and trivalent iron species in binary and ternary molten salt systems consisting of 1-ethyl-3-methylimidazolium chloride (EMICl) with iron chlorides, FeCl₂ and FeCl₃, was investigated as a candidate of the half-cell reactions of novel rechargeable redox batteries based on low temperature molten salt systems. A reversible one-electron redox reaction between divalent and trivalent iron species was observed on a platinum electrode in EMICl-FeCl₂-FeCl₃ system at 130°C. The voltammetric data indicated that divalent and trivalent iron species were FeCl₃^- and FeCl₄^- complex anions, respectively. Combined with another proper redox couple, this molten salt system can be utilized in a rechargeable redox battery on account of its low melting temperature and reversible redox reaction.

Original language	English
Pages (from-to)	327-332
Number of pages	6
Journal	Journal of Power Sources
Volume	109
Issue number	2
DOIs	https://doi.org/10.1016/S0378-7753(02)00077-0
Publication status	Published - 2002 Jul 1

Keywords

1-Ethyl-3-methylimidazolium
Iron chloride
Molten salt
Redox battery

ASJC Scopus subject areas

Renewable Energy, Sustainability and the Environment
Energy Engineering and Power Technology
Physical and Theoretical Chemistry
Electrical and Electronic Engineering

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1016/S0378-7753(02)00077-0

Cite this

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title = "Redox reaction in 1-ethyl-3-methylimidazolium-iron chlorides molten salt system for battery application",

abstract = "The redox reaction between divalent and trivalent iron species in binary and ternary molten salt systems consisting of 1-ethyl-3-methylimidazolium chloride (EMICl) with iron chlorides, FeCl2 and FeCl3, was investigated as a candidate of the half-cell reactions of novel rechargeable redox batteries based on low temperature molten salt systems. A reversible one-electron redox reaction between divalent and trivalent iron species was observed on a platinum electrode in EMICl-FeCl2-FeCl3 system at 130°C. The voltammetric data indicated that divalent and trivalent iron species were FeCl3- and FeCl4- complex anions, respectively. Combined with another proper redox couple, this molten salt system can be utilized in a rechargeable redox battery on account of its low melting temperature and reversible redox reaction.",

keywords = "1-Ethyl-3-methylimidazolium, Iron chloride, Molten salt, Redox battery",

author = "Yasushi Katayama and Isamu Konishiike and Takashi Miura and Tomiya Kishi",

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T1 - Redox reaction in 1-ethyl-3-methylimidazolium-iron chlorides molten salt system for battery application

AU - Katayama, Yasushi

AU - Konishiike, Isamu

AU - Miura, Takashi

AU - Kishi, Tomiya

PY - 2002/7/1

Y1 - 2002/7/1

N2 - The redox reaction between divalent and trivalent iron species in binary and ternary molten salt systems consisting of 1-ethyl-3-methylimidazolium chloride (EMICl) with iron chlorides, FeCl2 and FeCl3, was investigated as a candidate of the half-cell reactions of novel rechargeable redox batteries based on low temperature molten salt systems. A reversible one-electron redox reaction between divalent and trivalent iron species was observed on a platinum electrode in EMICl-FeCl2-FeCl3 system at 130°C. The voltammetric data indicated that divalent and trivalent iron species were FeCl3- and FeCl4- complex anions, respectively. Combined with another proper redox couple, this molten salt system can be utilized in a rechargeable redox battery on account of its low melting temperature and reversible redox reaction.

AB - The redox reaction between divalent and trivalent iron species in binary and ternary molten salt systems consisting of 1-ethyl-3-methylimidazolium chloride (EMICl) with iron chlorides, FeCl2 and FeCl3, was investigated as a candidate of the half-cell reactions of novel rechargeable redox batteries based on low temperature molten salt systems. A reversible one-electron redox reaction between divalent and trivalent iron species was observed on a platinum electrode in EMICl-FeCl2-FeCl3 system at 130°C. The voltammetric data indicated that divalent and trivalent iron species were FeCl3- and FeCl4- complex anions, respectively. Combined with another proper redox couple, this molten salt system can be utilized in a rechargeable redox battery on account of its low melting temperature and reversible redox reaction.

KW - 1-Ethyl-3-methylimidazolium

KW - Iron chloride

KW - Molten salt

KW - Redox battery

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Redox reaction in 1-ethyl-3-methylimidazolium-iron chlorides molten salt system for battery application

Abstract

Keywords

ASJC Scopus subject areas

UN SDGs

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