Regiocontrolled copolymerization of methyl acrylate with carbon monoxide

Akifumi Nakamura, Kagehiro Munakata, Takuya Kochi, Kyoko Nozaki

Research output: Contribution to journalArticle

34 Citations (Scopus)

Abstract

An alternating copolymer of methyl acrylate with carbon monoxide has been synthesized for the first time via coordination polymerization using palladium complexes of phosphine-sulfonic acid as catalysts. The highly controlled head-to-tail structure of the copolymer was confirmed by NMR spectra. Subsequent insertion of carbon monoxide and methyl acrylate to methylpalladium species provided γ-ketoalkylpalladium 2. The present system apparently conquered the difficulty in coordination-insertion of CO to 2.

Original languageEnglish
Pages (from-to)8128-8129
Number of pages2
JournalJournal of the American Chemical Society
Volume130
Issue number26
DOIs
Publication statusPublished - 2008 Jul 2

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Carbon Monoxide
Carbon monoxide
Copolymerization
phosphine
Copolymers
Palladium
Sulfonic Acids
Polymerization
Nuclear magnetic resonance
Catalysts
Acids
methyl acrylate

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Regiocontrolled copolymerization of methyl acrylate with carbon monoxide. / Nakamura, Akifumi; Munakata, Kagehiro; Kochi, Takuya; Nozaki, Kyoko.

In: Journal of the American Chemical Society, Vol. 130, No. 26, 02.07.2008, p. 8128-8129.

Research output: Contribution to journalArticle

Nakamura, Akifumi ; Munakata, Kagehiro ; Kochi, Takuya ; Nozaki, Kyoko. / Regiocontrolled copolymerization of methyl acrylate with carbon monoxide. In: Journal of the American Chemical Society. 2008 ; Vol. 130, No. 26. pp. 8128-8129.
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