Regioselective and stereoselective glycosylations utilizing organoboron compounds

Daisuke Takahashi, Masamichi Tanaka, Kazunobu Toshima

Research output: Contribution to journal › Short survey

1 Citation (Scopus)

Abstract

Development of regio- and stereoselective glycosylations leading to a specific hydroxyl group among several free hydroxyl groups is a challenging and long-standing research subject in carbohydrate chemistry. In this context, several efficient regio- and stereoselective glycosylation methods utilizing organoboron reagents, which can bind reversibly to cis-1,2- or 1,3-diols under mild conditions, have been reported. In this focused review article, several organoboron-mediated regio- and stereoselective glycosylations are described, including recently developed methods.

Original languageEnglish
Pages (from-to)E55-E62
JournalTrends in Glycoscience and Glycotechnology
Volume30
Issue number174
DOIs
Publication statusPublished - 2018 Jan 1

Fingerprint

Glycosylation
Hydroxyl Radical
Research Subjects
Carbohydrates

Keywords

  • Borinic acid
  • Boronic acid
  • Glycosylation
  • Organoboron compound
  • Regioselective
  • Stereoselective
  • Unprotected glycoside

ASJC Scopus subject areas

  • Biochemistry
  • Organic Chemistry

Cite this

Regioselective and stereoselective glycosylations utilizing organoboron compounds. / Takahashi, Daisuke; Tanaka, Masamichi; Toshima, Kazunobu.

In: Trends in Glycoscience and Glycotechnology, Vol. 30, No. 174, 01.01.2018, p. E55-E62.

Research output: Contribution to journal › Short survey

Takahashi, D, Tanaka, M & Toshima, K 2018, 'Regioselective and stereoselective glycosylations utilizing organoboron compounds', Trends in Glycoscience and Glycotechnology, vol. 30, no. 174, pp. E55-E62. https://doi.org/10.4052/tigg.1817.2E
Takahashi D, Tanaka M, Toshima K. Regioselective and stereoselective glycosylations utilizing organoboron compounds. Trends in Glycoscience and Glycotechnology. 2018 Jan 1;30(174):E55-E62. https://doi.org/10.4052/tigg.1817.2E
Takahashi, Daisuke ; Tanaka, Masamichi ; Toshima, Kazunobu. / Regioselective and stereoselective glycosylations utilizing organoboron compounds. In: Trends in Glycoscience and Glycotechnology. 2018 ; Vol. 30, No. 174. pp. E55-E62.
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